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प्रश्न
Give reasons for the following : H2Te is the strongest reducing agent amongst all the hydrides of Group 16 elements.
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उत्तर
As the size of the elements increases in the order O < S < Se < Te, the X−H bond strength decreases from H2O to H2Te and therefore, the bond dissociation enthalpy decreases. Hence, due to the increase in the tendency to release proton, the element's reducing tendency also increases. Therefore, H2Te is the strongest reducing agent amongst all the hydrides of Group 16 elements.
संबंधित प्रश्न
Account for the following: Oxygen shows catenation behavior less than sulphur.
a. Explain the trends in the following properties with reference to group 16:
1 Atomic radii and ionic radii
2 Density
3 ionisation enthalpy
4 Electronegativity
b. In the electolysis of AgNO3 solution 0.7g of Ag is deposited after a certain period of time. Calulate the quantity of electricity required in coulomb. (Molar mass of Ag is 107.9g mol-1)
Give reasons for the following : Oxygen has less electron gain enthalpy with negative sign than sulphur.
Why does NH3 form hydrogen bond but PH3 does not?
Why are halogens strong oxidising agents?
Arrange the following in the order of the property indicated against set :
H2O, H2S, H2Se, H2Te − increasing acidic character.
Explain the following properties of group 16 elements :
1) Electro negativity
2) Melting and boiling points
3) Metallic character
4) Allotropy
Give reactions for the following:
O – O single bond is weaker than S – S single bond.
______ is a radioactive element in group 16 elements.
Given below are two statements:
Statement I: The boiling point of hydrides of Group 16 elements follows the order:
H2O > H2Te > H2Se > H2S
Statement II: On the basis of molecular mass, H2O is expected to have a lower boiling point than the other members of the group but due to the presence of extensive H-bonding in H2O, it has a higher boiling point.
In the light of the above statements, choose the correct answer from the options given below:
