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प्रश्न
Strong reducing behaviour of \[\ce{H3PO2}\] is due to ______.
पर्याय
Low oxidation state of phosphorus
Presence of two –OH groups and one P–H bond
Presence of one –OH group and two P–H bonds
High electron gain enthalpy of phosphorus
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उत्तर
Strong reducing behaviour of \[\ce{H3PO2}\] is due to presence of one –OH group and two P–H bonds.
Explanation:
\[\ce{H3PO2}\] has one O – H group and two P – H bonds.
The existence of a P – H link gives phosphorus oxyacids their reducing characteristics. It has a strong proclivity for releasing protons. As a result, it demonstrates a decreasing nature.
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संबंधित प्रश्न
a. Explain the trends in the following properties with reference to group 16:
1 Atomic radii and ionic radii
2 Density
3 ionisation enthalpy
4 Electronegativity
b. In the electolysis of AgNO3 solution 0.7g of Ag is deposited after a certain period of time. Calulate the quantity of electricity required in coulomb. (Molar mass of Ag is 107.9g mol-1)
Account for the following : There is large difference between the melting and boiling points of oxygen and sulphur.
Give reasons for the following : H2Te is the strongest reducing agent amongst all the hydrides of Group 16 elements.
Give reasons for the following : Oxygen has less electron gain enthalpy with negative sign than sulphur.
List the important sources of sulphur.
Write the order of thermal stability of the hydrides of Group 16 elements.
Why is H2O a liquid and H2S a gas?
Which of the following does not react with oxygen directly?
Zn, Ti, Pt, Fe
Why does NH3 form hydrogen bond but PH3 does not?
The HNH angle value is higher than HPH, HAsH and HSbH angles. Why? [Hint: Can be explained on the basis of sp3 hybridisation in NH3 and only s−p bonding between hydrogen and other elements of the group].
Explain why inspite of nearly the same electronegativity, oxygen forms hydrogen bonding while chlorine does not.
Draw the structures of `H_3PO_2`
Arrange the following in the order of the property indicated against set :
H2O, H2S, H2Se, H2Te − increasing acidic character.
Give a reason for the following:
Fluorine gives only one oxide but chlorine gives a series of oxides.
The boiling points of hydrides of group 16 are in the order:
Which of the following statement is incorrect?
Match the items of Columns I and II and mark the correct option.
| Column I | Column II |
| (A) \[\ce{H2SO4}\] | (1) Highest electron gain enthalpy |
| (B) \[\ce{CCl3NO2}\] | (2) Chalcogen |
| (C) \[\ce{Cl2}\] | (3) Tear gas |
| (D) Sulphur | (4) Storage batteries |
Write a balanced chemical equation for the reaction showing catalytic oxidation of NH3 by atmospheric oxygen.
Which of the following compound is a peroxide?
These are physical properties of an elements.
- Sublimation enthalpy
- Ionisation enthalpy
- Hydration enthalpy
- Electron gain enthalpy
The total number of above properties that affect the reduction potential is ______. (Integer answer)
