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प्रश्न
Strong reducing behaviour of \[\ce{H3PO2}\] is due to ______.
विकल्प
Low oxidation state of phosphorus
Presence of two –OH groups and one P–H bond
Presence of one –OH group and two P–H bonds
High electron gain enthalpy of phosphorus
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उत्तर
Strong reducing behaviour of \[\ce{H3PO2}\] is due to presence of one –OH group and two P–H bonds.
Explanation:
\[\ce{H3PO2}\] has one O – H group and two P – H bonds.
The existence of a P – H link gives phosphorus oxyacids their reducing characteristics. It has a strong proclivity for releasing protons. As a result, it demonstrates a decreasing nature.
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संबंधित प्रश्न
Account for the following: Oxygen shows catenation behavior less than sulphur.
a. Explain the trends in the following properties with reference to group 16:
1 Atomic radii and ionic radii
2 Density
3 ionisation enthalpy
4 Electronegativity
b. In the electolysis of AgNO3 solution 0.7g of Ag is deposited after a certain period of time. Calulate the quantity of electricity required in coulomb. (Molar mass of Ag is 107.9g mol-1)
Give reasons for the following : H2Te is the strongest reducing agent amongst all the hydrides of Group 16 elements.
Give reasons for the following : Oxygen has less electron gain enthalpy with negative sign than sulphur.
Write the order of thermal stability of the hydrides of Group 16 elements.
Which of the following does not react with oxygen directly?
Zn, Ti, Pt, Fe
Why does NH3 form hydrogen bond but PH3 does not?
Knowing the electron gain enthalpy values for \[\ce{O -> O-}\] and \[\ce{O -> O^{2-}}\] as −141 and 702 kJ mol−1 respectively, how can you account for the formation of a large number of oxides having O2− species and not O−?
(Hint: Consider lattice energy factor in the formation of compounds).
Arrange the following in the order of property indicated for the given set:
F2, Cl2, Br2, I2 - increasing bond dissociation enthalpy.
Draw the structures of `H_3PO_2`
Arrange the following in the order of the property indicated against set :
H2O, H2S, H2Se, H2Te − increasing acidic character.
Give a reason for the following:
Fluorine gives only one oxide but chlorine gives a series of oxides.
The formation of \[\ce{O^+_2[PtF6]^-}\] is the basis for the formation of first xenon compound. This is because ____________.
Match the items of Columns I and II and mark the correct option.
| Column I | Column II |
| (A) \[\ce{H2SO4}\] | (1) Highest electron gain enthalpy |
| (B) \[\ce{CCl3NO2}\] | (2) Chalcogen |
| (C) \[\ce{Cl2}\] | (3) Tear gas |
| (D) Sulphur | (4) Storage batteries |
Given below are two statements labelled as Assertion (A) and Reason (R).
Assertion (A): Electron gain enthalpy of oxygen is less than that of Flourine but greater than Nitrogen.
Reason (R): Ionisation enthalpies of the elements follow the order Nitrogen > Oxygen > Fluorine.
Select the most appropriate answer from the options given below:
In forming (i) \[\ce{N2 -> N^{+}2}\] and (ii) \[\ce{O2 -> O^{+}2}\]; the electrons respectively are removed from:
These are physical properties of an elements.
- Sublimation enthalpy
- Ionisation enthalpy
- Hydration enthalpy
- Electron gain enthalpy
The total number of above properties that affect the reduction potential is ______. (Integer answer)
