Advertisements
Advertisements
प्रश्न
a. Explain the trends in the following properties with reference to group 16:
1 Atomic radii and ionic radii
2 Density
3 ionisation enthalpy
4 Electronegativity
b. In the electolysis of AgNO3 solution 0.7g of Ag is deposited after a certain period of time. Calulate the quantity of electricity required in coulomb. (Molar mass of Ag is 107.9g mol-1)
Advertisements
उत्तर
(a) Trends in 16-Group
(i) Atomic radii and ionic radii
Down the group atomic radii increases.
(ii) Density
Down the group density increased.
(iii) Ionization enthalpy
The Ist ionization enthapies of the elements of group 16 are unexpectedly lower, while their IInd ionization enthalpies are higher than those of the correspending element of group 15.
(iv) Electronegativity
The element of group 16 have higher value of electronegativity then the corresponding element of group 15.
(b) `"Mass of sub"=Q/96500xx"mole ratio"xx"mol mass"`
Mass of sub = 0.7 g
`"Mole ratio"=1/1`
Molar mass = 107.9
`:.0.7=Q/96500xx1xx107.9`
`Q=(0.7xx96500)/107.9`
`=67550/107.9`
=626.04
| Quantity of electricity = 626.04 C |
APPEARS IN
संबंधित प्रश्न
Give reasons: SO2 is reducing while TeO2 is an oxidising agent.
Account for the following : There is large difference between the melting and boiling points of oxygen and sulphur.
Give reasons for the following : H2Te is the strongest reducing agent amongst all the hydrides of Group 16 elements.
Give reasons for the following : Oxygen has less electron gain enthalpy with negative sign than sulphur.
Why does NH3 form hydrogen bond but PH3 does not?
The HNH angle value is higher than HPH, HAsH and HSbH angles. Why? [Hint: Can be explained on the basis of sp3 hybridisation in NH3 and only s−p bonding between hydrogen and other elements of the group].
Justify the placement of O, S, Se, Te and Po in the same group of the periodic table in terms of electronic configuration, oxidation state and hydride formation.
Why are halogens strong oxidising agents?
Arrange the following in the order of property indicated for the given set:
F2, Cl2, Br2, I2 - increasing bond dissociation enthalpy.
Give reasons Thermal stability decreases from H2O to H2Te.
Draw the structures of `H_3PO_2`
Explain the following properties of group 16 elements :
1) Electro negativity
2) Melting and boiling points
3) Metallic character
4) Allotropy
Arrange the following in order of the property indicated set.
HF, HCl, HBr, HI - decreasing bond enthalpy.
The boiling points of hydrides of group 16 are in the order:
The formation of \[\ce{O^+_2[PtF6]^-}\] is the basis for the formation of first xenon compound. This is because ____________.
Which of the following statement is incorrect?
Which of the following statements are correct?
(i) \[\ce{CaF2 + H2SO4 -> CaSO4 + 2HF}\]
(ii) \[\ce{2HI + H2SO4 -> I2 + SO2 + 2H2O}\]
(iii) \[\ce{Cu + 2H2SO4 -> CuSO4 + SO2 + 2H2O}\]
(iv) \[\ce{Nacl + H2SO4 -> NaHSO4 + HCl}\]
Out of \[\ce{H2O}\] and \[\ce{H2S}\], which one has higher bond angle and why?
The correct order of ΔiHs among the following elements is
Which of the following compound is a peroxide?
What is the basicity of \[\ce{H3PO4}\]?
______ is a radioactive element in group 16 elements.
