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Account for the Following : There is Large Difference Between the Melting and Boiling Points of Oxygen and Sulphur. - Chemistry

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प्रश्न

Account for the following : There is large difference between the melting and boiling points of oxygen and sulphur.

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उत्तर

The oxygen exists as a diatomic molecule, O2, while sulphur exists as a polyatomic molecule, S8. Hence, there is a large difference between the melting point and the boiling point of oxygen and sulphur.

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2014-2015 (March) Delhi Set 1

वीडियो ट्यूटोरियलVIEW ALL [2]

संबंधित प्रश्न

a. Explain the trends in the following properties with reference to group 16:

1 Atomic radii and ionic radii

2 Density

3 ionisation enthalpy

4 Electronegativity

b. In the electolysis of AgNO3 solution 0.7g of Ag is deposited after a certain period of time. Calulate the quantity of electricity required in coulomb. (Molar mass of Ag is 107.9g mol-1)

 


Why is H2O a liquid and H2S a gas?


The HNH angle value is higher than HPH, HAsH and HSbH angles. Why? [Hint: Can be explained on the basis of sp3 hybridisation in NH3 and only s−p bonding between hydrogen and other elements of the group].


Knowing the electron gain enthalpy values for \[\ce{O -> O-}\] and \[\ce{O -> O^{2-}}\] as −141 and 702 kJ mol−1 respectively, how can you account for the formation of a large number of oxides having O2− species and not O?

(Hint: Consider lattice energy factor in the formation of compounds).


Give reasons Thermal stability decreases from H2O to H2Te.


Arrange the following in the order of the property indicated against set :
H2O, H2S, H2Se, H2Te − increasing acidic character.


The boiling points of hydrides of group 16 are in the order:


Given below are two statements labelled as Assertion (A) and Reason (R).

Assertion (A): Electron gain enthalpy of oxygen is less than that of Flourine but greater than Nitrogen.

Reason (R): Ionisation enthalpies of the elements follow the order Nitrogen > Oxygen > Fluorine.

Select the most appropriate answer from the options given below:


Strong reducing behaviour of \[\ce{H3PO2}\] is due to ______.


Which of the following statements are correct?

(i) \[\ce{CaF2 + H2SO4 -> CaSO4 + 2HF}\]

(ii) \[\ce{2HI + H2SO4 -> I2 + SO2 + 2H2O}\]

(iii) \[\ce{Cu + 2H2SO4 -> CuSO4 + SO2 + 2H2O}\]

(iv) \[\ce{Nacl + H2SO4 -> NaHSO4 + HCl}\]


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