Advertisements
Advertisements
Question
Give reasons for the following : Oxygen has less electron gain enthalpy with negative sign than sulphur.
Advertisements
Solution
The elements of group 16 have two electrons less than the nearest noble gas configuration. Therefore, they have a high tendency to accept two additional electrons and hence have large negative electron gain enthalpies next only to the halogens. The electron gain enthalpy of oxygen is however least negative in this group. This is due to its small size. As a result of which, the electron – electron repulsions in the relatively small 2p-subshell are comparatively large and hence the incoming electrons are not accepted with the same ease in case of other elements of this group.
APPEARS IN
RELATED QUESTIONS
Account for the following: Oxygen shows catenation behavior less than sulphur.
Account for the following : There is large difference between the melting and boiling points of oxygen and sulphur.
List the important sources of sulphur.
Why are halogens strong oxidising agents?
Arrange the following in the order of property indicated for the given set:
F2, Cl2, Br2, I2 - increasing bond dissociation enthalpy.
Explain the following properties of group 16 elements :
1) Electro negativity
2) Melting and boiling points
3) Metallic character
4) Allotropy
The boiling points of hydrides of group 16 are in the order:
Which of the following statement is incorrect?
Match the items of Columns I and II and mark the correct option.
| Column I | Column II |
| (A) \[\ce{H2SO4}\] | (1) Highest electron gain enthalpy |
| (B) \[\ce{CCl3NO2}\] | (2) Chalcogen |
| (C) \[\ce{Cl2}\] | (3) Tear gas |
| (D) Sulphur | (4) Storage batteries |
Given below are two statements:
Statement I: The boiling point of hydrides of Group 16 elements follows the order:
H2O > H2Te > H2Se > H2S
Statement II: On the basis of molecular mass, H2O is expected to have a lower boiling point than the other members of the group but due to the presence of extensive H-bonding in H2O, it has a higher boiling point.
In the light of the above statements, choose the correct answer from the options given below:
