Advertisements
Advertisements
Question
Give reasons for the following : Oxygen has less electron gain enthalpy with negative sign than sulphur.
Advertisements
Solution
The elements of group 16 have two electrons less than the nearest noble gas configuration. Therefore, they have a high tendency to accept two additional electrons and hence have large negative electron gain enthalpies next only to the halogens. The electron gain enthalpy of oxygen is however least negative in this group. This is due to its small size. As a result of which, the electron – electron repulsions in the relatively small 2p-subshell are comparatively large and hence the incoming electrons are not accepted with the same ease in case of other elements of this group.
APPEARS IN
RELATED QUESTIONS
Write the order of thermal stability of the hydrides of Group 16 elements.
Which of the following does not react with oxygen directly?
Zn, Ti, Pt, Fe
Justify the placement of O, S, Se, Te and Po in the same group of the periodic table in terms of electronic configuration, oxidation state and hydride formation.
Knowing the electron gain enthalpy values for \[\ce{O -> O-}\] and \[\ce{O -> O^{2-}}\] as −141 and 702 kJ mol−1 respectively, how can you account for the formation of a large number of oxides having O2− species and not O−?
(Hint: Consider lattice energy factor in the formation of compounds).
Why are halogens strong oxidising agents?
Draw the structures of `H_3PO_2`
Explain the following properties of group 16 elements :
1) Electro negativity
2) Melting and boiling points
3) Metallic character
4) Allotropy
Write a balanced chemical equation for the reaction showing catalytic oxidation of NH3 by atmospheric oxygen.
Out of \[\ce{H2O}\] and \[\ce{H2S}\], which one has higher bond angle and why?
What is the basicity of \[\ce{H3PO4}\]?
