Advertisements
Advertisements
Question
While sulphur dioxide and hydrogen peroxide can act as oxidising as well as reducing agents in their reactions, ozone and nitric acid act only as oxidants. Why?
Advertisements
Solution
- In sulphur dioxide (SO2), the oxidation number (O.N.) of S is +4 and the range of the O.N. that S can have is from +6 to –2.
Therefore, SO2 can act as an oxidising as well as a reducing agent. - In hydrogen peroxide (H2O2), the O.N. of O is –1 and the range of the O.N. that O can have is from 0 to –2. O can sometimes also attain the oxidation numbers +1 and +2. Hence, H2O2 can act as an oxidising as well as a reducing agent.
- In ozone (O3), the O.N. of O is zero and the range of the O.N. that O can have is from 0 to –2. Therefore, the O.N. of O can only decrease in this case. Hence, O3 acts only as an oxidant.
- In nitric acid (HNO3), the O.N. of N is +5 and the range of the O.N. that N can have is from +5 to –3. Therefore, the O.N. of N can only decrease in this case. Hence, HNO3acts only as an oxidant.
APPEARS IN
RELATED QUESTIONS
Justify that the following reaction is redox reaction:
\[\ce{4BCl3(g) + 3LiAlH4(s) → 2B2H6(g) + 3LiCl(s) + 3 AlCl3(s)}\]
How do you count for the following observations?
When concentrated sulphuric acid is added to an inorganic mixture containing chloride, we get colourless pungent-smelling gas HCl, but if the mixture contains bromide then we get red vapour of bromine. Why?
Identify the substance oxidised, reduced, oxidising agent and reducing agent for the following reaction:
\[\ce{HCHO(l) + 2[Ag (NH3)2]+(aq) + 3OH–(aq) → 2Ag(s) + HCOO–(aq) + 4NH3(aq) + 2H2O(l)}\]
Identify the substance oxidised, reduced, oxidising agent and reducing agent for the following reaction:
\[\ce{HCHO (l) + 2Cu^{2+}(aq) + 5 OH–(aq) → Cu2O(s) + HCOO–(aq) + 3H2O(l)}\]
Consider the reactions:
\[\ce{2S_2O_3^{(2-)}(aq) + l_2(S) -> S_4O_6^{(2-)}(aq) + 2l-(aq)}\]
\[\ce{S_2O_3^{(2-)}(aq) + 2Br_2(l) + 5H_2O(l) -> 2SO_4^{2-} (aq) + 4Br-(aq) + 10H+ (aq)}\]
Why does the same reductant, thiosulphate react differently with iodine and bromine?
Refer to the periodic table given in your book and now answer the following questions:
Select the possible non-metals that can show disproportionation reaction.
Identify disproportionation reaction
Which of the following statement(s) is/are not true about the following decomposition reaction.
\[\ce{2KClO3 -> 2KCl + 3O2}\]
(i) Potassium is undergoing oxidation.
(ii) Chlorine is undergoing oxidation.
(iii) Oxygen is reduced.
(iv) None of the species are undergoing oxidation or reduction.
Identify the correct statements with reference to the given reaction.
\[\ce{P4 + 3OH- + 3H2O -> PH3 + 3H2PO^{-}2}\]
(i) Phosphorus is undergoing reduction only.
(ii) Phosphorus is undergoing oxidation only.
(iii) Phosphorus is undergoing oxidation as well as reduction.
(iv) Hydrogen is undergoing neither oxidation nor reduction.
Why does fluorine not show disporportionation reaction?
Write redox couples involved in the reactions given.
\[\ce{Fe + Cd^{2+} -> Cd + Fe^{2+}}\]
Find out the oxidation number of chlorine in the following compounds and arrange them in increasing order of oxidation number of chlorine.
\[\ce{NaClO4, NaClO3, NaClO, KClO2, Cl2O7, ClO3, Cl2O, NaCl, Cl2 , ClO2}\].
Which oxidation state is not present in any of the above compounds?
Which of the following statement is CORRECT for the decomposition reaction of KClO3?
\[\ce{2KClO3 → 2KCl +3O2}\]
Which of the following examples does not represent disproportionation?
An acidified manganate solution undergoes disproportionation reaction. The spin-only magnetic moment value of the product having manganese in a higher oxidation state is ______ B.M. (Nearest integer)
The reaction of sulphur in alkaline medium is given below:
\[\ce{S8(s) + {a} OH^-(aq) -> {b} S^{2-}(aq) + {c} S2O^{2-}3(aq) + {d} H2O(l)}\]
The values of 'a' are ______. (Integer answer)
The species given below that does NOT show a disproportionation reaction is ______.
\[\ce{H2O2 -> H2O + O2}\]
This represents ______.
