हिंदी
कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान कक्षा ११

While sulphur dioxide and hydrogen peroxide can act as oxidising as well as reducing agents in their reactions, ozone and nitric acid act only as oxidants. Why?

Advertisements
Advertisements

प्रश्न

While sulphur dioxide and hydrogen peroxide can act as oxidising as well as reducing agents in their reactions, ozone and nitric acid act only as oxidants. Why?

संक्षेप में उत्तर
Advertisements

उत्तर

  1. In sulphur dioxide (SO2), the oxidation number (O.N.) of S is +4 and the range of the O.N. that S can have is from +6 to –2.
    Therefore, SO2 can act as an oxidising as well as a reducing agent.
  2. In hydrogen peroxide (H2O2), the O.N. of O is –1 and the range of the O.N. that O can have is from 0 to –2. O can sometimes also attain the oxidation numbers +1 and +2. Hence, H2O2 can act as an oxidising as well as a reducing agent.
  3. In ozone (O3), the O.N. of O is zero and the range of the O.N. that O can have is from 0 to –2. Therefore, the O.N. of O can only decrease in this case. Hence, O3 acts only as an oxidant.
  4. In nitric acid (HNO3), the O.N. of N is +5 and the range of the O.N. that N can have is from +5 to –3. Therefore, the O.N. of N can only decrease in this case. Hence, HNO3acts only as an oxidant.
shaalaa.com
  क्या इस प्रश्न या उत्तर में कोई त्रुटि है?
अध्याय 7: Redox Reactions - EXERCISES [पृष्ठ २८०]

APPEARS IN

एनसीईआरटी Chemistry Part 1 and 2 [English] Class 11
अध्याय 7 Redox Reactions
EXERCISES | Q 8.8 | पृष्ठ २८०

संबंधित प्रश्न

Justify that the following reaction is redox reaction:

\[\ce{Fe2O3(s) + 3CO(g) → 2Fe(s) + 3CO2(g)}\]


Justify that the following reaction is redox reaction:

\[\ce{2K(s) + F2(g) → 2K+F– (s)}\]


Identify the substance oxidised, reduced, oxidising agent and reducing agent for the following reaction:

\[\ce{HCHO(l) + 2[Ag (NH3)2]+(aq) + 3OH–(aq) → 2Ag(s) + HCOO–(aq) + 4NH3(aq) + 2H2O(l)}\]


Identify the substance oxidised, reduced, oxidising agent and reducing agent for the following reaction:

\[\ce{HCHO (l) + 2Cu^{2+}(aq) + 5 OH–(aq) → Cu2O(s) + HCOO–(aq) + 3H2O(l)}\]


Identify the substance oxidised, reduced, oxidising agent and reducing agent for the following reaction:

\[\ce{Pb(s) + PbO2(s) + 2H2SO4(aq) → 2PbSO4(s) + 2H2O(l)}\]


Consider the reactions:

  1. \[\ce{H3PO2(aq) + 4 AgNO3(aq) + 2 H2O(l) → H3PO4(aq) + 4Ag(s) + 4HNO3(aq)}\]
  2. \[\ce{H3PO2(aq) + 2CuSO4(aq) + 2 H2O(l) → H3PO4(aq) + 2Cu(s) + H2SO4(aq)}\]
  3. \[\ce{C6H5CHO(l) + 2[Ag (NH3)2]+(aq) + 3OH–(aq) → C6H5COO–(aq) + 2Ag(s) + 4NH3 (aq) + 2 H2O(l)}\]
  4. \[\ce{C6H5CHO(l) + 2Cu^{2+}(aq) + 5OH–(aq) → No change observed}\]

What inference do you draw about the behaviour of Ag+ and Cu2+ from these reactions?


What sorts of informations can you draw from the following reaction ?

\[\ce{{(CN)}_{2(g)} + 2OH-_{(aq)} -> CN-_{(aq)} + CNO-_{(aq)} + H_2O_{(l)}}\]


Refer to the periodic table given in your book and now answer the following question:

Select three metals that can show disproportionation reaction.


Identify the correct statements with reference to the given reaction.

\[\ce{P4 + 3OH- + 3H2O -> PH3 + 3H2PO^{-}2}\]

(i) Phosphorus is undergoing reduction only.

(ii) Phosphorus is undergoing oxidation only.

(iii) Phosphorus is undergoing oxidation as well as reduction.

(iv) Hydrogen is undergoing neither oxidation nor reduction.


Assertion (A): Redox couple is the combination of oxidised and reduced form of a substance involved in an oxidation or reduction half cell.

Reason (R): In the representation \[\ce{E^Θ_{Fe^{3+}/Fe^{2+}}}\] and \[\ce{E^Θ_{Cu^{2+}/Cu}, Fe^{3+}/Fe^{2+}}\] and \[\ce{Cu^{2+}/Cu}\] are redox couples.


Why does fluorine not show disporportionation reaction?


Write redox couples involved in the reactions given.

\[\ce{Fe + Cd^{2+} -> Cd + Fe^{2+}}\]


Find out the oxidation number of chlorine in the following compounds and arrange them in increasing order of oxidation number of chlorine.

\[\ce{NaClO4, NaClO3, NaClO, KClO2, Cl2O7, ClO3, Cl2O, NaCl, Cl2 , ClO2}\].

Which oxidation state is not present in any of the above compounds?


Which of the following reactions is the metal displacement reaction? Choose the right option.


An acidified manganate solution undergoes disproportionation reaction. The spin-only magnetic moment value of the product having manganese in a higher oxidation state is ______ B.M. (Nearest integer)


The species given below that does NOT show a disproportionation reaction is ______.


\[\ce{H2O2 -> H2O + O2}\]

This represents ______.


For the decomposition reaction \[\ce{NH2COONH4 (s) <=> 2NH3 (g) + CO2 (g)}\] the Kp = 2.9 × 10-5 atm3. The total pressure of gases at equilibrium when 1 mol of \[\ce{NH2COONH4 (s)}\] was taken initially could be ______.


Share
Notifications

Englishहिंदीमराठी


      Forgot password?
Use app×