Advertisements
Advertisements
प्रश्न
Find out the oxidation number of chlorine in the following compounds and arrange them in increasing order of oxidation number of chlorine.
\[\ce{NaClO4, NaClO3, NaClO, KClO2, Cl2O7, ClO3, Cl2O, NaCl, Cl2 , ClO2}\].
Which oxidation state is not present in any of the above compounds?
Advertisements
उत्तर
We can calculate the oxidation states by:
\[\ce{NaClO4}\] Oxidation no. of chlorine = +7
Suppose oxidation number of chlorine is x then, 1 + x + 4 × (−2) = 0
∴ x – 7 = 0
x = +7
We can calculate, the oxidation states, as given below:
\[\ce{NaClO3}\] Oxidation no. of chlorine = +5
\[\ce{NaClO}\] Oxidation no. of chlorine = +1
\[\ce{KClO2}\] Oxidation no. of chlorine = +3
\[\ce{Cl2O7}\] Oxidation no. of chlorine = +7
\[\ce{ClO3}\] Oxidation no. of chlorine = +6
\[\ce{Cl2O}\] Oxidation no. of chlorine = +1
\[\ce{NaCl}\] Oxidation no. of chlorine = −1
\[\ce{Cl2}\] Oxidation no. of chlorine = 0
\[\ce{ClO2}\] Oxidation no. of chlorine = +4.
Oxidation state (+2) is not present in any of the above compounds.
APPEARS IN
संबंधित प्रश्न
Justify that the following reaction is redox reaction:
\[\ce{4BCl3(g) + 3LiAlH4(s) → 2B2H6(g) + 3LiCl(s) + 3 AlCl3(s)}\]
Justify that the following reaction is redox reaction:
\[\ce{2K(s) + F2(g) → 2K+F– (s)}\]
Suggest a list of the substances where carbon can exhibit oxidation states from –4 to +4 and nitrogen from –3 to +5.
Identify the substance oxidised, reduced, oxidising agent and reducing agent for the following reaction:
\[\ce{N2H4(l) + 2H2O2(l) → N2(g) + 4H2O(l)}\]
Consider the reactions:
- \[\ce{H3PO2(aq) + 4 AgNO3(aq) + 2 H2O(l) → H3PO4(aq) + 4Ag(s) + 4HNO3(aq)}\]
- \[\ce{H3PO2(aq) + 2CuSO4(aq) + 2 H2O(l) → H3PO4(aq) + 2Cu(s) + H2SO4(aq)}\]
- \[\ce{C6H5CHO(l) + 2[Ag (NH3)2]+(aq) + 3OH–(aq) → C6H5COO–(aq) + 2Ag(s) + 4NH3 (aq) + 2 H2O(l)}\]
- \[\ce{C6H5CHO(l) + 2Cu^{2+}(aq) + 5OH–(aq) → No change observed}\]
What inference do you draw about the behaviour of Ag+ and Cu2+ from these reactions?
What sorts of informations can you draw from the following reaction ?
\[\ce{{(CN)}_{2(g)} + 2OH-_{(aq)} -> CN-_{(aq)} + CNO-_{(aq)} + H_2O_{(l)}}\]
Refer to the periodic table given in your book and now answer the following questions:
Select the possible non-metals that can show disproportionation reaction.
Refer to the periodic table given in your book and now answer the following question:
Select three metals that can show disproportionation reaction.
Identify disproportionation reaction
Which of the following elements does not show disproportionation tendency?
Which of the following statement(s) is/are not true about the following decomposition reaction.
\[\ce{2KClO3 -> 2KCl + 3O2}\]
(i) Potassium is undergoing oxidation.
(ii) Chlorine is undergoing oxidation.
(iii) Oxygen is reduced.
(iv) None of the species are undergoing oxidation or reduction.
\[\ce{MnO^{2-}4}\] undergoes disproportionation reaction in acidic medium but \[\ce{MnO^{-}4}\] does not. Give reason.
Assertion (A): The decomposition of hydrogen peroxide to form water and oxygen is an example of disproportionation reaction.
Reason (R): The oxygen of peroxide is in –1 oxidation state and it is converted to zero oxidation state in \[\ce{O2}\] and –2 oxidation state in \[\ce{H2O}\].
Write redox couples involved in the reactions given.
\[\ce{Cu + Zn^{2+} ->Cu^{2+} + Zn}\]
Write redox couples involved in the reactions given.
\[\ce{Fe + Cd^{2+} -> Cd + Fe^{2+}}\]
Which of the following examples does not represent disproportionation?
An acidified manganate solution undergoes disproportionation reaction. The spin-only magnetic moment value of the product having manganese in a higher oxidation state is ______ B.M. (Nearest integer)
The species given below that does NOT show a disproportionation reaction is ______.
\[\ce{H2O2 -> H2O + O2}\]
This represents ______.
