Advertisements
Advertisements
प्रश्न
Justify that the following reaction is redox reaction:
\[\ce{4BCl3(g) + 3LiAlH4(s) → 2B2H6(g) + 3LiCl(s) + 3 AlCl3(s)}\]
Advertisements
उत्तर
The oxidation number of each element in the given reaction can be represented as:
+3 -1 +1 +3 -1 -3 +1 +1 -1 +3 -1
\[\ce{4BCl3(g) + 3LiAlH4(s) → 2B2H6(g) + 3LiCl(s) + 3 AlCl3(s)}\]
In this reaction, the oxidation number of B decreases from +3 in BCl3 to –3 in B2H6. i.e., BCl3 is reduced to B2H6. Also, the oxidation number of H increases from –1 in LiAlH4 to +1 in B2H6 i.e., LiAlH4 is oxidized to B2H6. Hence, the given reaction is a redox reaction.
APPEARS IN
संबंधित प्रश्न
Justify that the following reaction is redox reaction:
\[\ce{Fe2O3(s) + 3CO(g) → 2Fe(s) + 3CO2(g)}\]
Justify that the following reaction is redox reaction:
\[\ce{4 NH3(g) + 5 O2(g) → 4NO(g) + 6H2O(g)}\]
Identify the substance oxidised, reduced, oxidising agent and reducing agent for the following reaction:
\[\ce{HCHO(l) + 2[Ag (NH3)2]+(aq) + 3OH–(aq) → 2Ag(s) + HCOO–(aq) + 4NH3(aq) + 2H2O(l)}\]
Identify the substance oxidised, reduced, oxidising agent and reducing agent for the following reaction:
\[\ce{N2H4(l) + 2H2O2(l) → N2(g) + 4H2O(l)}\]
Identify the substance oxidised, reduced, oxidising agent and reducing agent for the following reaction:
\[\ce{Pb(s) + PbO2(s) + 2H2SO4(aq) → 2PbSO4(s) + 2H2O(l)}\]
Why does the following reaction occur?
\[\ce{XeO^{4-}_6 (aq) + 2F- (aq) + 6H+ (aq) -> XeO3(g) + F_2(g) + 3H_2O(l)}\]
What conclusion about the compound Na4XeO6 (of which `"XeO"_6^(4+)` is a part) can be drawn from the reaction.
Arrange the following metals in the order in which they displace each other from the solution of their salts.
Al, Cu, Fe, Mg and Zn.
Which of the following is not an example of redox reaction?
Which of the following elements does not show disproportionation tendency?
Which of the following statement(s) is/are not true about the following decomposition reaction.
\[\ce{2KClO3 -> 2KCl + 3O2}\]
(i) Potassium is undergoing oxidation.
(ii) Chlorine is undergoing oxidation.
(iii) Oxygen is reduced.
(iv) None of the species are undergoing oxidation or reduction.
Identify the correct statements with reference to the given reaction.
\[\ce{P4 + 3OH- + 3H2O -> PH3 + 3H2PO^{-}2}\]
(i) Phosphorus is undergoing reduction only.
(ii) Phosphorus is undergoing oxidation only.
(iii) Phosphorus is undergoing oxidation as well as reduction.
(iv) Hydrogen is undergoing neither oxidation nor reduction.
Assertion (A): The decomposition of hydrogen peroxide to form water and oxygen is an example of disproportionation reaction.
Reason (R): The oxygen of peroxide is in –1 oxidation state and it is converted to zero oxidation state in \[\ce{O2}\] and –2 oxidation state in \[\ce{H2O}\].
Why does fluorine not show disporportionation reaction?
Write redox couples involved in the reactions given.
\[\ce{Mg + Fe^{2+} -> Mg^{2+} + Fe}\]
Find out the oxidation number of chlorine in the following compounds and arrange them in increasing order of oxidation number of chlorine.
\[\ce{NaClO4, NaClO3, NaClO, KClO2, Cl2O7, ClO3, Cl2O, NaCl, Cl2 , ClO2}\].
Which oxidation state is not present in any of the above compounds?
Which of the following examples does not represent disproportionation?
An acidified manganate solution undergoes disproportionation reaction. The spin-only magnetic moment value of the product having manganese in a higher oxidation state is ______ B.M. (Nearest integer)
\[\ce{H2O2 -> H2O + O2}\]
This represents ______.
For the decomposition reaction \[\ce{NH2COONH4 (s) <=> 2NH3 (g) + CO2 (g)}\] the Kp = 2.9 × 10-5 atm3. The total pressure of gases at equilibrium when 1 mol of \[\ce{NH2COONH4 (s)}\] was taken initially could be ______.
