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प्रश्न
Refer to the periodic table given in your book and now answer the following questions:
Select the possible non-metals that can show disproportionation reaction.
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उत्तर
In disproportionation reactions, one of the reacting substances always contains an element that can exist in at least three oxidation states.
P4, Cl2, and S can show disproportionation reactions as these elements can exist in three or more oxidation states.
संबंधित प्रश्न
Justify that the following reaction is redox reaction:
\[\ce{2K(s) + F2(g) → 2K+F– (s)}\]
Justify that the following reaction is redox reaction:
\[\ce{4 NH3(g) + 5 O2(g) → 4NO(g) + 6H2O(g)}\]
Fluorine reacts with ice and results in the change: \[\ce{H2O(s) + F2(g) → HF(g) + HOF(g)}\]
Justify that this reaction is a redox reaction.
How do you count for the following observations?
When concentrated sulphuric acid is added to an inorganic mixture containing chloride, we get colourless pungent-smelling gas HCl, but if the mixture contains bromide then we get red vapour of bromine. Why?
Identify the substance oxidised, reduced, oxidising agent and reducing agent for the following reaction:
\[\ce{2AgBr (s) + C6H6O2(aq) → 2Ag(s) + 2HBr (aq) + C6H4O2(aq)}\]
Identify the substance oxidised, reduced, oxidising agent and reducing agent for the following reaction:
\[\ce{HCHO(l) + 2[Ag (NH3)2]+(aq) + 3OH–(aq) → 2Ag(s) + HCOO–(aq) + 4NH3(aq) + 2H2O(l)}\]
Identify the substance oxidised, reduced, oxidising agent and reducing agent for the following reaction:
\[\ce{Pb(s) + PbO2(s) + 2H2SO4(aq) → 2PbSO4(s) + 2H2O(l)}\]
Consider the reactions:
\[\ce{2S_2O_3^{(2-)}(aq) + l_2(S) -> S_4O_6^{(2-)}(aq) + 2l-(aq)}\]
\[\ce{S_2O_3^{(2-)}(aq) + 2Br_2(l) + 5H_2O(l) -> 2SO_4^{2-} (aq) + 4Br-(aq) + 10H+ (aq)}\]
Why does the same reductant, thiosulphate react differently with iodine and bromine?
Why does the following reaction occur?
\[\ce{XeO^{4-}_6 (aq) + 2F- (aq) + 6H+ (aq) -> XeO3(g) + F_2(g) + 3H_2O(l)}\]
What conclusion about the compound Na4XeO6 (of which `"XeO"_6^(4+)` is a part) can be drawn from the reaction.
Consider the reactions:
- \[\ce{H3PO2(aq) + 4 AgNO3(aq) + 2 H2O(l) → H3PO4(aq) + 4Ag(s) + 4HNO3(aq)}\]
- \[\ce{H3PO2(aq) + 2CuSO4(aq) + 2 H2O(l) → H3PO4(aq) + 2Cu(s) + H2SO4(aq)}\]
- \[\ce{C6H5CHO(l) + 2[Ag (NH3)2]+(aq) + 3OH–(aq) → C6H5COO–(aq) + 2Ag(s) + 4NH3 (aq) + 2 H2O(l)}\]
- \[\ce{C6H5CHO(l) + 2Cu^{2+}(aq) + 5OH–(aq) → No change observed}\]
What inference do you draw about the behaviour of Ag+ and Cu2+ from these reactions?
What sorts of informations can you draw from the following reaction ?
\[\ce{{(CN)}_{2(g)} + 2OH-_{(aq)} -> CN-_{(aq)} + CNO-_{(aq)} + H_2O_{(l)}}\]
Arrange the following metals in the order in which they displace each other from the solution of their salts.
Al, Cu, Fe, Mg and Zn.
Which of the following is not an example of redox reaction?
Identify disproportionation reaction
Identify the correct statements with reference to the given reaction.
\[\ce{P4 + 3OH- + 3H2O -> PH3 + 3H2PO^{-}2}\]
(i) Phosphorus is undergoing reduction only.
(ii) Phosphorus is undergoing oxidation only.
(iii) Phosphorus is undergoing oxidation as well as reduction.
(iv) Hydrogen is undergoing neither oxidation nor reduction.
Write redox couples involved in the reactions given.
\[\ce{Cu + Zn^{2+} ->Cu^{2+} + Zn}\]
Find out the oxidation number of chlorine in the following compounds and arrange them in increasing order of oxidation number of chlorine.
\[\ce{NaClO4, NaClO3, NaClO, KClO2, Cl2O7, ClO3, Cl2O, NaCl, Cl2 , ClO2}\].
Which oxidation state is not present in any of the above compounds?
