Advertisements
Advertisements
Question
Find out the oxidation number of chlorine in the following compounds and arrange them in increasing order of oxidation number of chlorine.
\[\ce{NaClO4, NaClO3, NaClO, KClO2, Cl2O7, ClO3, Cl2O, NaCl, Cl2 , ClO2}\].
Which oxidation state is not present in any of the above compounds?
Advertisements
Solution
We can calculate the oxidation states by:
\[\ce{NaClO4}\] Oxidation no. of chlorine = +7
Suppose oxidation number of chlorine is x then, 1 + x + 4 × (−2) = 0
∴ x – 7 = 0
x = +7
We can calculate, the oxidation states, as given below:
\[\ce{NaClO3}\] Oxidation no. of chlorine = +5
\[\ce{NaClO}\] Oxidation no. of chlorine = +1
\[\ce{KClO2}\] Oxidation no. of chlorine = +3
\[\ce{Cl2O7}\] Oxidation no. of chlorine = +7
\[\ce{ClO3}\] Oxidation no. of chlorine = +6
\[\ce{Cl2O}\] Oxidation no. of chlorine = +1
\[\ce{NaCl}\] Oxidation no. of chlorine = −1
\[\ce{Cl2}\] Oxidation no. of chlorine = 0
\[\ce{ClO2}\] Oxidation no. of chlorine = +4.
Oxidation state (+2) is not present in any of the above compounds.
APPEARS IN
RELATED QUESTIONS
Justify that the following reaction is redox reaction:
\[\ce{CuO(s) + H2(g) → Cu(s) + H2O(g)}\]
Justify that the following reaction is redox reaction:
\[\ce{Fe2O3(s) + 3CO(g) → 2Fe(s) + 3CO2(g)}\]
Justify that the following reaction is redox reaction:
\[\ce{4 NH3(g) + 5 O2(g) → 4NO(g) + 6H2O(g)}\]
Suggest a list of the substances where carbon can exhibit oxidation states from –4 to +4 and nitrogen from –3 to +5.
How do you count for the following observations?
When concentrated sulphuric acid is added to an inorganic mixture containing chloride, we get colourless pungent-smelling gas HCl, but if the mixture contains bromide then we get red vapour of bromine. Why?
Identify the substance oxidised, reduced, oxidising agent and reducing agent for the following reaction:
\[\ce{HCHO(l) + 2[Ag (NH3)2]+(aq) + 3OH–(aq) → 2Ag(s) + HCOO–(aq) + 4NH3(aq) + 2H2O(l)}\]
Identify the substance oxidised, reduced, oxidising agent and reducing agent for the following reaction:
\[\ce{N2H4(l) + 2H2O2(l) → N2(g) + 4H2O(l)}\]
Identify the substance oxidised, reduced, oxidising agent and reducing agent for the following reaction:
\[\ce{Pb(s) + PbO2(s) + 2H2SO4(aq) → 2PbSO4(s) + 2H2O(l)}\]
Consider the reactions:
- \[\ce{H3PO2(aq) + 4 AgNO3(aq) + 2 H2O(l) → H3PO4(aq) + 4Ag(s) + 4HNO3(aq)}\]
- \[\ce{H3PO2(aq) + 2CuSO4(aq) + 2 H2O(l) → H3PO4(aq) + 2Cu(s) + H2SO4(aq)}\]
- \[\ce{C6H5CHO(l) + 2[Ag (NH3)2]+(aq) + 3OH–(aq) → C6H5COO–(aq) + 2Ag(s) + 4NH3 (aq) + 2 H2O(l)}\]
- \[\ce{C6H5CHO(l) + 2Cu^{2+}(aq) + 5OH–(aq) → No change observed}\]
What inference do you draw about the behaviour of Ag+ and Cu2+ from these reactions?
Refer to the periodic table given in your book and now answer the following questions:
Select the possible non-metals that can show disproportionation reaction.
Refer to the periodic table given in your book and now answer the following question:
Select three metals that can show disproportionation reaction.
Which of the following elements does not show disproportionation tendency?
\[\ce{MnO^{2-}4}\] undergoes disproportionation reaction in acidic medium but \[\ce{MnO^{-}4}\] does not. Give reason.
Write redox couples involved in the reactions given.
\[\ce{Mg + Fe^{2+} -> Mg^{2+} + Fe}\]
Write redox couples involved in the reactions given.
\[\ce{Br2 + 2Cl- -> Cl2 + 2Br-}\]
Which of the following reactions is the metal displacement reaction? Choose the right option.
The reaction of sulphur in alkaline medium is given below:
\[\ce{S8(s) + {a} OH^-(aq) -> {b} S^{2-}(aq) + {c} S2O^{2-}3(aq) + {d} H2O(l)}\]
The values of 'a' are ______. (Integer answer)
For the decomposition reaction \[\ce{NH2COONH4 (s) <=> 2NH3 (g) + CO2 (g)}\] the Kp = 2.9 × 10-5 atm3. The total pressure of gases at equilibrium when 1 mol of \[\ce{NH2COONH4 (s)}\] was taken initially could be ______.
