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While sulphur dioxide and hydrogen peroxide can act as oxidising as well as reducing agents in their reactions, ozone and nitric acid act only as oxidants. Why?

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प्रश्न

While sulphur dioxide and hydrogen peroxide can act as oxidising as well as reducing agents in their reactions, ozone and nitric acid act only as oxidants. Why?

थोडक्यात उत्तर
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उत्तर

  1. In sulphur dioxide (SO2), the oxidation number (O.N.) of S is +4 and the range of the O.N. that S can have is from +6 to –2.
    Therefore, SO2 can act as an oxidising as well as a reducing agent.
  2. In hydrogen peroxide (H2O2), the O.N. of O is –1 and the range of the O.N. that O can have is from 0 to –2. O can sometimes also attain the oxidation numbers +1 and +2. Hence, H2O2 can act as an oxidising as well as a reducing agent.
  3. In ozone (O3), the O.N. of O is zero and the range of the O.N. that O can have is from 0 to –2. Therefore, the O.N. of O can only decrease in this case. Hence, O3 acts only as an oxidant.
  4. In nitric acid (HNO3), the O.N. of N is +5 and the range of the O.N. that N can have is from +5 to –3. Therefore, the O.N. of N can only decrease in this case. Hence, HNO3acts only as an oxidant.
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पाठ 7: Redox Reactions - EXERCISES [पृष्ठ २८०]

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एनसीईआरटी Chemistry Part 1 and 2 [English] Class 11
पाठ 7 Redox Reactions
EXERCISES | Q 8.8 | पृष्ठ २८०

संबंधित प्रश्‍न

Justify that the following reaction is redox reaction:

\[\ce{CuO(s) + H2(g) → Cu(s) + H2O(g)}\]


Justify that the following reaction is redox reaction:

\[\ce{Fe2O3(s) + 3CO(g) → 2Fe(s) + 3CO2(g)}\]


Justify that the following reaction is redox reaction:

\[\ce{4 NH3(g) + 5 O2(g) → 4NO(g) + 6H2O(g)}\]


Suggest a list of the substances where carbon can exhibit oxidation states from –4 to +4 and nitrogen from –3 to +5.


Identify the substance oxidised, reduced, oxidising agent and reducing agent for the following reaction:

\[\ce{2AgBr (s) + C6H6O2(aq) → 2Ag(s) + 2HBr (aq) + C6H4O2(aq)}\]


Identify the substance oxidised, reduced, oxidising agent and reducing agent for the following reaction:

\[\ce{HCHO(l) + 2[Ag (NH3)2]+(aq) + 3OH–(aq) → 2Ag(s) + HCOO–(aq) + 4NH3(aq) + 2H2O(l)}\]


Identify the substance oxidised, reduced, oxidising agent and reducing agent for the following reaction:

\[\ce{HCHO (l) + 2Cu^{2+}(aq) + 5 OH–(aq) → Cu2O(s) + HCOO–(aq) + 3H2O(l)}\]


Identify the substance oxidised, reduced, oxidising agent and reducing agent for the following reaction:

\[\ce{Pb(s) + PbO2(s) + 2H2SO4(aq) → 2PbSO4(s) + 2H2O(l)}\]


Refer to the periodic table given in your book and now answer the following question:

Select three metals that can show disproportionation reaction.


Arrange the following metals in the order in which they displace each other from the solution of their salts.

Al, Cu, Fe, Mg and Zn.


Which of the following elements does not show disproportionation tendency?


Which of the following statement(s) is/are not true about the following decomposition reaction.

\[\ce{2KClO3 -> 2KCl + 3O2}\]

(i) Potassium is undergoing oxidation.

(ii) Chlorine is undergoing oxidation.

(iii) Oxygen is reduced.

(iv) None of the species are undergoing oxidation or reduction.


Write redox couples involved in the reactions given.

\[\ce{Fe + Cd^{2+} -> Cd + Fe^{2+}}\]


Which of the following statement is CORRECT for the decomposition reaction of KClO3

\[\ce{2KClO3 → 2KCl +3O2}\]


Which of the following reactions is the metal displacement reaction? Choose the right option.


An acidified manganate solution undergoes disproportionation reaction. The spin-only magnetic moment value of the product having manganese in a higher oxidation state is ______ B.M. (Nearest integer)


For the decomposition reaction \[\ce{NH2COONH4 (s) <=> 2NH3 (g) + CO2 (g)}\] the Kp = 2.9 × 10-5 atm3. The total pressure of gases at equilibrium when 1 mol of \[\ce{NH2COONH4 (s)}\] was taken initially could be ______.


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