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Identify the correct statements with reference to the given reaction. PX4+3OHX−+3HX2O⟶PHX3+3HX2POX2− (i) Phosphorus is undergoing reduction only. (ii) Phosphorus is undergoing oxidati

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प्रश्न

Identify the correct statements with reference to the given reaction.

\[\ce{P4 + 3OH- + 3H2O -> PH3 + 3H2PO^{-}2}\]

(i) Phosphorus is undergoing reduction only.

(ii) Phosphorus is undergoing oxidation only.

(iii) Phosphorus is undergoing oxidation as well as reduction.

(iv) Hydrogen is undergoing neither oxidation nor reduction.

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उत्तर

(iii) Phosphorus is undergoing oxidation as well as reduction.

(iv) Hydrogen is undergoing neither oxidation nor reduction.

Explanation:

The given reaction is as below-

\[\ce{P4 + 3OH- + 3H2O -> PH3 + 3H2PO^{-}2}\]

The above reaction is a kind of disproportionate reaction in which phosphorous is being reduced as well as oxidized whereas hydrogen remains same in +1 oxidation state. 

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पाठ 8: Redox Reactions - Multiple Choice Questions (Type - I) [पृष्ठ १०७]

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एनसीईआरटी एक्झांप्लर Chemistry Exemplar [English] Class 11
पाठ 8 Redox Reactions
Multiple Choice Questions (Type - I) | Q 15 | पृष्ठ १०७

संबंधित प्रश्‍न

Justify that the following reaction is redox reaction:

\[\ce{CuO(s) + H2(g) → Cu(s) + H2O(g)}\]


Justify that the following reaction is redox reaction:

\[\ce{4BCl3(g) + 3LiAlH4(s) → 2B2H6(g) + 3LiCl(s) + 3 AlCl3(s)}\]


Fluorine reacts with ice and results in the change: \[\ce{H2O(s) + F2(g) → HF(g) + HOF(g)}\]

Justify that this reaction is a redox reaction.


Identify the substance oxidised, reduced, oxidising agent and reducing agent for the following reaction:

\[\ce{HCHO (l) + 2Cu^{2+}(aq) + 5 OH–(aq) → Cu2O(s) + HCOO–(aq) + 3H2O(l)}\]


Identify the substance oxidised, reduced, oxidising agent and reducing agent for the following reaction:

\[\ce{N2H4(l) + 2H2O2(l) → N2(g) + 4H2O(l)}\]


Consider the reactions:

  1. \[\ce{H3PO2(aq) + 4 AgNO3(aq) + 2 H2O(l) → H3PO4(aq) + 4Ag(s) + 4HNO3(aq)}\]
  2. \[\ce{H3PO2(aq) + 2CuSO4(aq) + 2 H2O(l) → H3PO4(aq) + 2Cu(s) + H2SO4(aq)}\]
  3. \[\ce{C6H5CHO(l) + 2[Ag (NH3)2]+(aq) + 3OH–(aq) → C6H5COO–(aq) + 2Ag(s) + 4NH3 (aq) + 2 H2O(l)}\]
  4. \[\ce{C6H5CHO(l) + 2Cu^{2+}(aq) + 5OH–(aq) → No change observed}\]

What inference do you draw about the behaviour of Ag+ and Cu2+ from these reactions?


What sorts of informations can you draw from the following reaction ?

\[\ce{{(CN)}_{2(g)} + 2OH-_{(aq)} -> CN-_{(aq)} + CNO-_{(aq)} + H_2O_{(l)}}\]


Refer to the periodic table given in your book and now answer the following questions:

Select the possible non-metals that can show disproportionation reaction.


Which of the following is not an example of redox reaction?


Which of the following elements does not show disproportionation tendency?


\[\ce{MnO^{2-}4}\] undergoes disproportionation reaction in acidic medium but \[\ce{MnO^{-}4}\] does not. Give reason.


Assertion (A): Redox couple is the combination of oxidised and reduced form of a substance involved in an oxidation or reduction half cell.

Reason (R): In the representation \[\ce{E^Θ_{Fe^{3+}/Fe^{2+}}}\] and \[\ce{E^Θ_{Cu^{2+}/Cu}, Fe^{3+}/Fe^{2+}}\] and \[\ce{Cu^{2+}/Cu}\] are redox couples.


Write redox couples involved in the reactions given.

\[\ce{Mg + Fe^{2+} -> Mg^{2+} + Fe}\]


Write redox couples involved in the reactions given.

\[\ce{Fe + Cd^{2+} -> Cd + Fe^{2+}}\]


Which of the following examples does not represent disproportionation?


Which of the following reactions is the metal displacement reaction? Choose the right option.


The species given below that does NOT show a disproportionation reaction is ______.


\[\ce{H2O2 -> H2O + O2}\]

This represents ______.


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