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MnOX42− undergoes disproportionation reaction in acidic medium but MnOX4− does not. Give reason. - Chemistry

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प्रश्न

\[\ce{MnO^{2-}4}\] undergoes disproportionation reaction in acidic medium but \[\ce{MnO^{-}4}\] does not. Give reason.

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उत्तर

In \[\ce{MnO^{2-}4}\], Mn is in highest oxidation state that is +7 hence here manganese cannot undergo oxidation that is why disproportionate is not possible whereas in \[\ce{MnO^{2-}4}\] manganese is in +6 oxidation state which can be oxidized as well as reduced.

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Oxidation Number - Types of Redox Reactions
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पाठ 8: Redox Reactions - Multiple Choice Questions (Type - I) [पृष्ठ १०७]

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एनसीईआरटी एक्झांप्लर Chemistry [English] Class 11
पाठ 8 Redox Reactions
Multiple Choice Questions (Type - I) | Q 18 | पृष्ठ १०७

संबंधित प्रश्‍न

Justify that the following reaction is redox reaction:

\[\ce{Fe2O3(s) + 3CO(g) → 2Fe(s) + 3CO2(g)}\]


Justify that the following reaction is redox reaction:

\[\ce{2K(s) + F2(g) → 2K+F– (s)}\]


While sulphur dioxide and hydrogen peroxide can act as oxidising as well as reducing agents in their reactions, ozone and nitric acid act only as oxidants. Why?


Identify the substance oxidised, reduced, oxidising agent and reducing agent for the following reaction:

\[\ce{HCHO(l) + 2[Ag (NH3)2]+(aq) + 3OH–(aq) → 2Ag(s) + HCOO–(aq) + 4NH3(aq) + 2H2O(l)}\]


Identify the substance oxidised, reduced, oxidising agent and reducing agent for the following reaction:

\[\ce{HCHO (l) + 2Cu^{2+}(aq) + 5 OH–(aq) → Cu2O(s) + HCOO–(aq) + 3H2O(l)}\]


Identify the substance oxidised, reduced, oxidising agent and reducing agent for the following reaction:

\[\ce{N2H4(l) + 2H2O2(l) → N2(g) + 4H2O(l)}\]


Identify the substance oxidised, reduced, oxidising agent and reducing agent for the following reaction:

\[\ce{Pb(s) + PbO2(s) + 2H2SO4(aq) → 2PbSO4(s) + 2H2O(l)}\]


Why does the following reaction occur?

\[\ce{XeO^{4-}_6 (aq) + 2F- (aq) + 6H+ (aq) -> XeO3(g) + F_2(g) + 3H_2O(l)}\]

What conclusion about the compound Na4XeO6 (of which `"XeO"_6^(4+)` is a part) can be drawn from the reaction.


What sorts of informations can you draw from the following reaction ?

\[\ce{{(CN)}_{2(g)} + 2OH-_{(aq)} -> CN-_{(aq)} + CNO-_{(aq)} + H_2O_{(l)}}\]


Arrange the following metals in the order in which they displace each other from the solution of their salts.

Al, Cu, Fe, Mg and Zn.


Identify disproportionation reaction


Assertion (A): The decomposition of hydrogen peroxide to form water and oxygen is an example of disproportionation reaction.

Reason (R): The oxygen of peroxide is in –1 oxidation state and it is converted to zero oxidation state in \[\ce{O2}\] and –2 oxidation state in \[\ce{H2O}\].


Write redox couples involved in the reactions given.

\[\ce{Mg + Fe^{2+} -> Mg^{2+} + Fe}\]


Write redox couples involved in the reactions given.

\[\ce{Fe + Cd^{2+} -> Cd + Fe^{2+}}\]


Which of the following examples does not represent disproportionation?


Which of the following reactions is the metal displacement reaction? Choose the right option.


An acidified manganate solution undergoes disproportionation reaction. The spin-only magnetic moment value of the product having manganese in a higher oxidation state is ______ B.M. (Nearest integer)


The reaction of sulphur in alkaline medium is given below:

\[\ce{S8(s) + {a} OH^-(aq) -> {b} S^{2-}(aq) + {c} S2O^{2-}3(aq) + {d} H2O(l)}\]

The values of 'a' are ______. (Integer answer)


The species given below that does NOT show a disproportionation reaction is ______.


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