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Why does fluorine not show disporportionation reaction?

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प्रश्न

Why does fluorine not show disporportionation reaction?

दीर्घउत्तर
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उत्तर

Disproportionate is defined as the reaction in which one compound of intermediate oxidation state converts to two compounds, one of higher and one of lower oxidation states So, to occur such type of redox reaction, the element should exist in at least three oxidation states. So that element present in the intermediate state and it can change to both higher and lower oxidation state during disproportionate reaction. Fluorine is the most electronegative element and a strong oxidizing agent and is the smallest in size of all the halogens. It does not show a positive oxidation state (shows only −1 oxidation state) and hence, does not undergo disproportionate reaction.

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पाठ 8: Redox Reactions - Multiple Choice Questions (Type - I) [पृष्ठ ११०]

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एनसीईआरटी एक्झांप्लर Chemistry [English] Class 11
पाठ 8 Redox Reactions
Multiple Choice Questions (Type - I) | Q 35 | पृष्ठ ११०

संबंधित प्रश्‍न

Justify that the following reaction is redox reaction:

\[\ce{Fe2O3(s) + 3CO(g) → 2Fe(s) + 3CO2(g)}\]


Justify that the following reaction is redox reaction:

\[\ce{4 NH3(g) + 5 O2(g) → 4NO(g) + 6H2O(g)}\]


Suggest a list of the substances where carbon can exhibit oxidation states from –4 to +4 and nitrogen from –3 to +5.


How do you count for the following observations?

When concentrated sulphuric acid is added to an inorganic mixture containing chloride, we get colourless pungent-smelling gas HCl, but if the mixture contains bromide then we get red vapour of bromine. Why?


Identify the substance oxidised, reduced, oxidising agent and reducing agent for the following reaction:

\[\ce{2AgBr (s) + C6H6O2(aq) → 2Ag(s) + 2HBr (aq) + C6H4O2(aq)}\]


Identify the substance oxidised, reduced, oxidising agent and reducing agent for the following reaction:

\[\ce{HCHO(l) + 2[Ag (NH3)2]+(aq) + 3OH–(aq) → 2Ag(s) + HCOO–(aq) + 4NH3(aq) + 2H2O(l)}\]


Identify the substance oxidised, reduced, oxidising agent and reducing agent for the following reaction:

\[\ce{N2H4(l) + 2H2O2(l) → N2(g) + 4H2O(l)}\]


Identify the substance oxidised, reduced, oxidising agent and reducing agent for the following reaction:

\[\ce{Pb(s) + PbO2(s) + 2H2SO4(aq) → 2PbSO4(s) + 2H2O(l)}\]


Consider the reactions:

  1. \[\ce{H3PO2(aq) + 4 AgNO3(aq) + 2 H2O(l) → H3PO4(aq) + 4Ag(s) + 4HNO3(aq)}\]
  2. \[\ce{H3PO2(aq) + 2CuSO4(aq) + 2 H2O(l) → H3PO4(aq) + 2Cu(s) + H2SO4(aq)}\]
  3. \[\ce{C6H5CHO(l) + 2[Ag (NH3)2]+(aq) + 3OH–(aq) → C6H5COO–(aq) + 2Ag(s) + 4NH3 (aq) + 2 H2O(l)}\]
  4. \[\ce{C6H5CHO(l) + 2Cu^{2+}(aq) + 5OH–(aq) → No change observed}\]

What inference do you draw about the behaviour of Ag+ and Cu2+ from these reactions?


Refer to the periodic table given in your book and now answer the following questions:

Select the possible non-metals that can show disproportionation reaction.


Identify disproportionation reaction


Identify the correct statements with reference to the given reaction.

\[\ce{P4 + 3OH- + 3H2O -> PH3 + 3H2PO^{-}2}\]

(i) Phosphorus is undergoing reduction only.

(ii) Phosphorus is undergoing oxidation only.

(iii) Phosphorus is undergoing oxidation as well as reduction.

(iv) Hydrogen is undergoing neither oxidation nor reduction.


Write redox couples involved in the reactions given.

\[\ce{Mg + Fe^{2+} -> Mg^{2+} + Fe}\]


Write redox couples involved in the reactions given.

\[\ce{Fe + Cd^{2+} -> Cd + Fe^{2+}}\]


Find out the oxidation number of chlorine in the following compounds and arrange them in increasing order of oxidation number of chlorine.

\[\ce{NaClO4, NaClO3, NaClO, KClO2, Cl2O7, ClO3, Cl2O, NaCl, Cl2 , ClO2}\].

Which oxidation state is not present in any of the above compounds?


In an experiment O3 undergo decomposition as \[\ce{O3 -> O2 + O}\] by the radiations of wavelength 310 Å. The total energy falling on the O3 gas molecules is 2.4 × 1026 eV and quantum yield of the reaction is 0.2.

The volume strength of the H2O2 solution which is obtained from reaction of 1 l H2O and nascent oxygen [O] obtained from the above reactions is (Assuming no change in volume of H2O)

\[\ce{H2O + O -> H2O2}\]

[Given: Na (Avogadro's No.) = 6 × 1023]


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