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Why does fluorine not show disporportionation reaction? - Chemistry

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प्रश्न

Why does fluorine not show disporportionation reaction?

दीर्घउत्तर
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उत्तर

Disproportionate is defined as the reaction in which one compound of intermediate oxidation state converts to two compounds, one of higher and one of lower oxidation states So, to occur such type of redox reaction, the element should exist in at least three oxidation states. So that element present in the intermediate state and it can change to both higher and lower oxidation state during disproportionate reaction. Fluorine is the most electronegative element and a strong oxidizing agent and is the smallest in size of all the halogens. It does not show a positive oxidation state (shows only −1 oxidation state) and hence, does not undergo disproportionate reaction.

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Oxidation Number - Types of Redox Reactions
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पाठ 8: Redox Reactions - Multiple Choice Questions (Type - I) [पृष्ठ ११०]

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एनसीईआरटी एक्झांप्लर Chemistry [English] Class 11
पाठ 8 Redox Reactions
Multiple Choice Questions (Type - I) | Q 35 | पृष्ठ ११०

संबंधित प्रश्‍न

Justify that the following reaction is redox reaction:

\[\ce{Fe2O3(s) + 3CO(g) → 2Fe(s) + 3CO2(g)}\]


Justify that the following reaction is redox reaction:

\[\ce{4BCl3(g) + 3LiAlH4(s) → 2B2H6(g) + 3LiCl(s) + 3 AlCl3(s)}\]


Justify that the following reaction is redox reaction:

\[\ce{4 NH3(g) + 5 O2(g) → 4NO(g) + 6H2O(g)}\]


How do you count for the following observations?

When concentrated sulphuric acid is added to an inorganic mixture containing chloride, we get colourless pungent-smelling gas HCl, but if the mixture contains bromide then we get red vapour of bromine. Why?


Identify the substance oxidised, reduced, oxidising agent and reducing agent for the following reaction:

\[\ce{N2H4(l) + 2H2O2(l) → N2(g) + 4H2O(l)}\]


Consider the reactions:

\[\ce{2S_2O_3^{(2-)}(aq) + l_2(S) -> S_4O_6^{(2-)}(aq) + 2l-(aq)}\]

\[\ce{S_2O_3^{(2-)}(aq) + 2Br_2(l) + 5H_2O(l) -> 2SO_4^{2-} (aq) + 4Br-(aq) + 10H+ (aq)}\]

Why does the same reductant, thiosulphate react differently with iodine and bromine?


Why does the following reaction occur?

\[\ce{XeO^{4-}_6 (aq) + 2F- (aq) + 6H+ (aq) -> XeO3(g) + F_2(g) + 3H_2O(l)}\]

What conclusion about the compound Na4XeO6 (of which `"XeO"_6^(4+)` is a part) can be drawn from the reaction.


Consider the reactions:

  1. \[\ce{H3PO2(aq) + 4 AgNO3(aq) + 2 H2O(l) → H3PO4(aq) + 4Ag(s) + 4HNO3(aq)}\]
  2. \[\ce{H3PO2(aq) + 2CuSO4(aq) + 2 H2O(l) → H3PO4(aq) + 2Cu(s) + H2SO4(aq)}\]
  3. \[\ce{C6H5CHO(l) + 2[Ag (NH3)2]+(aq) + 3OH–(aq) → C6H5COO–(aq) + 2Ag(s) + 4NH3 (aq) + 2 H2O(l)}\]
  4. \[\ce{C6H5CHO(l) + 2Cu^{2+}(aq) + 5OH–(aq) → No change observed}\]

What inference do you draw about the behaviour of Ag+ and Cu2+ from these reactions?


Which of the following is not an example of redox reaction?


Identify disproportionation reaction


Which of the following elements does not show disproportionation tendency?


Which of the following statement(s) is/are not true about the following decomposition reaction.

\[\ce{2KClO3 -> 2KCl + 3O2}\]

(i) Potassium is undergoing oxidation.

(ii) Chlorine is undergoing oxidation.

(iii) Oxygen is reduced.

(iv) None of the species are undergoing oxidation or reduction.


Write redox couples involved in the reactions given.

\[\ce{Cu + Zn^{2+} ->Cu^{2+} + Zn}\]


Write redox couples involved in the reactions given.

\[\ce{Fe + Cd^{2+} -> Cd + Fe^{2+}}\]


Which of the following statement is CORRECT for the decomposition reaction of KClO3

\[\ce{2KClO3 → 2KCl +3O2}\]


Which of the following examples does not represent disproportionation?


An acidified manganate solution undergoes disproportionation reaction. The spin-only magnetic moment value of the product having manganese in a higher oxidation state is ______ B.M. (Nearest integer)


The species given below that does NOT show a disproportionation reaction is ______.


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