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प्रश्न
Suggest a list of the substances where carbon can exhibit oxidation states from –4 to +4 and nitrogen from –3 to +5.
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उत्तर
The substances where carbon can exhibit oxidation states from –4 to +4 are listed in the following table.
| Substance | O.N. of carbon |
| CH2Cl2 | 0 |
| ClC≡CCl | +1 |
| HC≡CH | –1 |
| CHCl3, CO | +2 |
| CH3Cl | –2 |
| Cl3C – CCl3 | +3 |
| H3C – CH3 | –3 |
| CCl4, CO2 | +4 |
| CH4 | –4 |
The substances where nitrogen can exhibit oxidation states from –3 to +5 are listed in the following table
| Substance | O.N. of nitrogen |
| N2 | 0 |
| N2O | +1 |
| N2H2 | –1 |
| NO | +2 |
| N2H4 | –2 |
| N2O3 | +3 |
| NH3 | –3 |
| NO2 | +4 |
| N2O5 | +5 |
संबंधित प्रश्न
Justify that the following reaction is redox reaction:
\[\ce{Fe2O3(s) + 3CO(g) → 2Fe(s) + 3CO2(g)}\]
Justify that the following reaction is redox reaction:
\[\ce{4 NH3(g) + 5 O2(g) → 4NO(g) + 6H2O(g)}\]
While sulphur dioxide and hydrogen peroxide can act as oxidising as well as reducing agents in their reactions, ozone and nitric acid act only as oxidants. Why?
How do you count for the following observations?
When concentrated sulphuric acid is added to an inorganic mixture containing chloride, we get colourless pungent-smelling gas HCl, but if the mixture contains bromide then we get red vapour of bromine. Why?
Identify the substance oxidised, reduced, oxidising agent and reducing agent for the following reaction:
\[\ce{2AgBr (s) + C6H6O2(aq) → 2Ag(s) + 2HBr (aq) + C6H4O2(aq)}\]
Identify the substance oxidised, reduced, oxidising agent and reducing agent for the following reaction:
\[\ce{HCHO(l) + 2[Ag (NH3)2]+(aq) + 3OH–(aq) → 2Ag(s) + HCOO–(aq) + 4NH3(aq) + 2H2O(l)}\]
Identify the substance oxidised, reduced, oxidising agent and reducing agent for the following reaction:
\[\ce{HCHO (l) + 2Cu^{2+}(aq) + 5 OH–(aq) → Cu2O(s) + HCOO–(aq) + 3H2O(l)}\]
Consider the reactions:
- \[\ce{H3PO2(aq) + 4 AgNO3(aq) + 2 H2O(l) → H3PO4(aq) + 4Ag(s) + 4HNO3(aq)}\]
- \[\ce{H3PO2(aq) + 2CuSO4(aq) + 2 H2O(l) → H3PO4(aq) + 2Cu(s) + H2SO4(aq)}\]
- \[\ce{C6H5CHO(l) + 2[Ag (NH3)2]+(aq) + 3OH–(aq) → C6H5COO–(aq) + 2Ag(s) + 4NH3 (aq) + 2 H2O(l)}\]
- \[\ce{C6H5CHO(l) + 2Cu^{2+}(aq) + 5OH–(aq) → No change observed}\]
What inference do you draw about the behaviour of Ag+ and Cu2+ from these reactions?
What sorts of informations can you draw from the following reaction ?
\[\ce{{(CN)}_{2(g)} + 2OH-_{(aq)} -> CN-_{(aq)} + CNO-_{(aq)} + H_2O_{(l)}}\]
Refer to the periodic table given in your book and now answer the following questions:
Select the possible non-metals that can show disproportionation reaction.
Refer to the periodic table given in your book and now answer the following question:
Select three metals that can show disproportionation reaction.
Which of the following elements does not show disproportionation tendency?
Which of the following statement(s) is/are not true about the following decomposition reaction.
\[\ce{2KClO3 -> 2KCl + 3O2}\]
(i) Potassium is undergoing oxidation.
(ii) Chlorine is undergoing oxidation.
(iii) Oxygen is reduced.
(iv) None of the species are undergoing oxidation or reduction.
\[\ce{MnO^{2-}4}\] undergoes disproportionation reaction in acidic medium but \[\ce{MnO^{-}4}\] does not. Give reason.
Write redox couples involved in the reactions given.
\[\ce{Fe + Cd^{2+} -> Cd + Fe^{2+}}\]
Which of the following statement is CORRECT for the decomposition reaction of KClO3?
\[\ce{2KClO3 → 2KCl +3O2}\]
An acidified manganate solution undergoes disproportionation reaction. The spin-only magnetic moment value of the product having manganese in a higher oxidation state is ______ B.M. (Nearest integer)
The reaction of sulphur in alkaline medium is given below:
\[\ce{S8(s) + {a} OH^-(aq) -> {b} S^{2-}(aq) + {c} S2O^{2-}3(aq) + {d} H2O(l)}\]
The values of 'a' are ______. (Integer answer)
\[\ce{H2O2 -> H2O + O2}\]
This represents ______.
