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Assertion (A): The decomposition of hydrogen peroxide to form water and oxygen is an example of disproportionation reaction. Reason (R): The oxygen of peroxide is in –1 oxidation state and

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प्रश्न

Assertion (A): The decomposition of hydrogen peroxide to form water and oxygen is an example of disproportionation reaction.

Reason (R): The oxygen of peroxide is in –1 oxidation state and it is converted to zero oxidation state in \[\ce{O2}\] and –2 oxidation state in \[\ce{H2O}\].

पर्याय

  • Both A and R are true and R is the correct explanation of A.

  • Both A and R are true but R is not the correct explanation of A.

  • A is true but R is false.

  • Both A and R are false.

MCQ
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उत्तर

Both A and R are true and R is the correct explanation of A.

Explanation:

Here the oxygen of peroxide, which is present in –1 state, is converted to zero oxidation state in \[\ce{O2}\] undergoing oxidation and decreases to –2 oxidation state in \[\ce{H2O}\] undergoing reduction.

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  या प्रश्नात किंवा उत्तरात काही त्रुटी आहे का?
पाठ 8: Redox Reactions - Multiple Choice Questions (Type - I) [पृष्ठ ११०]

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एनसीईआरटी एक्झांप्लर Chemistry Exemplar [English] Class 11
पाठ 8 Redox Reactions
Multiple Choice Questions (Type - I) | Q 31 | पृष्ठ ११०

संबंधित प्रश्‍न

Justify that the following reaction is redox reaction:

\[\ce{4BCl3(g) + 3LiAlH4(s) → 2B2H6(g) + 3LiCl(s) + 3 AlCl3(s)}\]


Justify that the following reaction is redox reaction:

\[\ce{2K(s) + F2(g) → 2K+F– (s)}\]


Justify that the following reaction is redox reaction:

\[\ce{4 NH3(g) + 5 O2(g) → 4NO(g) + 6H2O(g)}\]


Fluorine reacts with ice and results in the change: \[\ce{H2O(s) + F2(g) → HF(g) + HOF(g)}\]

Justify that this reaction is a redox reaction.


How do you count for the following observations?

When concentrated sulphuric acid is added to an inorganic mixture containing chloride, we get colourless pungent-smelling gas HCl, but if the mixture contains bromide then we get red vapour of bromine. Why?


Identify the substance oxidised, reduced, oxidising agent and reducing agent for the following reaction:

\[\ce{2AgBr (s) + C6H6O2(aq) → 2Ag(s) + 2HBr (aq) + C6H4O2(aq)}\]


Identify the substance oxidised, reduced, oxidising agent and reducing agent for the following reaction:

\[\ce{HCHO(l) + 2[Ag (NH3)2]+(aq) + 3OH–(aq) → 2Ag(s) + HCOO–(aq) + 4NH3(aq) + 2H2O(l)}\]


Identify the substance oxidised, reduced, oxidising agent and reducing agent for the following reaction:

\[\ce{HCHO (l) + 2Cu^{2+}(aq) + 5 OH–(aq) → Cu2O(s) + HCOO–(aq) + 3H2O(l)}\]


Why does the following reaction occur?

\[\ce{XeO^{4-}_6 (aq) + 2F- (aq) + 6H+ (aq) -> XeO3(g) + F_2(g) + 3H_2O(l)}\]

What conclusion about the compound Na4XeO6 (of which `"XeO"_6^(4+)` is a part) can be drawn from the reaction.


Which of the following is not an example of redox reaction?


\[\ce{MnO^{2-}4}\] undergoes disproportionation reaction in acidic medium but \[\ce{MnO^{-}4}\] does not. Give reason.


Why does fluorine not show disporportionation reaction?


Write redox couples involved in the reactions given.

\[\ce{Cu + Zn^{2+} ->Cu^{2+} + Zn}\]


Write redox couples involved in the reactions given.

\[\ce{Fe + Cd^{2+} -> Cd + Fe^{2+}}\]


Which of the following examples does not represent disproportionation?


An acidified manganate solution undergoes disproportionation reaction. The spin-only magnetic moment value of the product having manganese in a higher oxidation state is ______ B.M. (Nearest integer)


\[\ce{H2O2 -> H2O + O2}\]

This represents ______.


In an experiment O3 undergo decomposition as \[\ce{O3 -> O2 + O}\] by the radiations of wavelength 310 Å. The total energy falling on the O3 gas molecules is 2.4 × 1026 eV and quantum yield of the reaction is 0.2.

The volume strength of the H2O2 solution which is obtained from reaction of 1 l H2O and nascent oxygen [O] obtained from the above reactions is (Assuming no change in volume of H2O)

\[\ce{H2O + O -> H2O2}\]

[Given: Na (Avogadro's No.) = 6 × 1023]


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