Advertisements
Advertisements
Question
Consider the reaction:
\[\ce{6 CO2(g) + 6H2O(l) → C6 H12O6(aq) + 6O2(g)}\]
Why it is more appropriate to write these reaction as:
\[\ce{6CO2(g) + 12H2O(l) → C6 H12O6(aq) + 6H2O(l) + 6O2(g)}\]
Also, suggest a technique to investigate the path of the redox reactions.
Advertisements
Solution
The process of photosynthesis involves two steps.
Step 1:
H2O decomposes to give H2 and O2.
Step 2:
The H2 produced in step 1 reduces CO2, thereby producing glucose (C6H12O6) and H2O.
\[\ce{6CO_{2(g)} + 12H_{2(g)} -> C_6H_12O_{6(s)} + 6H_2O_{(l)}}\]
Now, the net reaction of the process is given as:
| \[\ce{2H_2O_{(l)} -> 2H_{2(g)} + O_{2(g)} ] × 6}\] |
| \[\ce{6CO_{2(g)} + 12H_{2(g)} -> C_6H_12O_{6(g)} + 6H_2O_{(l)}}\] |
|
\[\ce{6CO_{2(g)} + 12H_2O_{(l)} -> C_6H_12O_{6(g)} + 6H_2O_{(l)} + 6O_{2(g)}}\] |
It is more appropriate to write the reaction as given above because water molecules are also produced in the process of photosynthesis.
The path of this reaction can be investigated by using radioactive H2O18 in place of H2O.
RELATED QUESTIONS
The compound AgF2 is an unstable compound. However, if formed, the compound acts as a very strong oxidizing agent. Why?
How do you count for the following observations?
Though alkaline potassium permanganate and acidic potassium permanganate both are used as oxidants, yet in the manufacture of benzoic acid from toluene we use alcoholic potassium permanganate as an oxidant. Why? Write a balanced redox equation for the reaction.
Balance the following equation in basic medium by ion-electron method and oxidation number methods and identify the oxidising agent and the reducing agent.
\[\ce{P4(s) + OH–(aq) —> PH3(g) + HPO^–_2(aq)}\]
Chlorine is used to purify drinking water. Excess of chlorine is harmful. The excess of chlorine is removed by treating with sulphur dioxide. Present a balanced equation for this redox change taking place in water.
Choose the correct option.
For the following redox reactions, find the correct statement.
\[\ce{Sn^{2⊕} + 2Fe^{3⊕}->Sn^{4⊕} + 2Fe^{2⊕}}\]
Justify that the following reaction is redox reaction; identify the species oxidized/reduced, which acts as an oxidant and which acts as a reductant.
\[\ce{2Cu2O_{(S)} + Cu2S_{(S)}->6Cu_{(S)} + SO2_{(g)}}\]
Balance the following reaction by oxidation number method.
\[\ce{Cr2O^2-_{7(aq)} + SO^2-_{3(aq)}->Cr^3+_{ (aq)} + SO^2-_{4(aq)}(acidic)}\]
Balance the following redox equation by half-reaction method.
\[\ce{H2C2O_{4(aq)} + MnO^-_{4(aq)}->CO2_{(g)} + Mn^2+_{( aq)}(acidic)}\]
Write balanced chemical equation for the following reactions:
Permanganate ion \[\ce{(MnO^{-}4)}\] reacts with sulphur dioxide gas in acidic medium to produce \[\ce{Mn^{2+}}\] and hydrogen sulphate ion.
Write balanced chemical equation for the following reactions:
Dichlorine heptaoxide \[\ce{(Cl2O7)}\] in gaseous state combines with an aqueous solution of hydrogen peroxide in acidic medium to give chlorite ion \[\ce{(ClO^{-}2)}\] and oxygen gas. (Balance by ion-electron method)
Balance the following equations by the oxidation number method.
\[\ce{Fe^{2+} + H^{+} + Cr2O^{2-}7 -> Cr^{3+} + Fe^{3+} + H2O}\]
Identify the redox reactions out of the following reactions and identify the oxidising and reducing agents in them.
\[\ce{3HCl (aq) + HNO3 (aq) -> Cl2 (g) + NOCl (g) + 2H2O (l)}\]
Identify the redox reactions out of the following reactions and identify the oxidising and reducing agents in them.
\[\ce{HgCl2 (aq) + 2KI (aq) -> HgI2 (s) + 2KCl (aq)}\]
Identify the redox reactions out of the following reactions and identify the oxidising and reducing agents in them.
\[\ce{Fe2O3 (s) + 3CO (g) ->[Δ] 2Fe (s) + 3CO2 (g)}\]
Balance the following ionic equations.
\[\ce{Cr2O^{2-}7 + Fe^{2+} + H+ -> Cr^{3+} + Fe^{3+} + H2O}\]
Balance the following ionic equations.
\[\ce{MnO^{-}4 + SO^{2-}3 + H^{+} -> Mn^{2+} + SO^{2-}4 + H2O}\]
Balance the following ionic equations.
\[\ce{MnO^{-}4 + H^{+} + Br^{-} -> Mn^{2+} + Br2 + H2O}\]
In the reaction of oxalate with permanganate in an acidic medium, the number of electrons involved in producing one molecule of CO2 is ______.
On balancing the given redox reaction,
\[\ce{aCr2O7^2- + Bso3^2- (aq) + CH+ (aq) -> 2aCr^3+ (aq) + bSO4^2- (aq) + c(H2O(1)/2}\]
the coefficients a, b and c are found to be, respectively:
