Advertisements
Advertisements
Question
Which of the carbon atoms present in the molecule given below are asymmetric?
\[\begin{array}{cc}
\phantom{}\ce{HO}\phantom{.....}\ce{OH}\phantom{..}\ce{H}\phantom{.....}\ce{O}\phantom{..}\\
\phantom{..}\backslash\phantom{.....}|\phantom{....}|\phantom{.....}//\phantom{.}\\
\ce{\overset{a}{C} - \overset{b}{C} - \overset{c}{C} - \overset{d}{C}}\\
\phantom{..}//\phantom{.....}|\phantom{....}|\phantom{....}\phantom{.}\backslash\phantom{...}\\
\phantom{}\ce{O}\phantom{......}\ce{H}\phantom{...}\ce{OH}\phantom{...}\ce{H}\phantom{}\\
\end{array}\]
Options
a, b, c, d
b, c
a, d
a, b, c
Advertisements
Solution
b, c
Explanation:
Carbon has four valencies. If a carbon atom satisfies all of its four valencies with four different groups then it is termed asymmetric/chiral carbon. In the given compound, b and c carbon are bonded to four different groups, so these are asymmetric.
APPEARS IN
RELATED QUESTIONS
Draw the structure of the major monohalo product in the following reaction:

Name the following halide according to the IUPAC system and classify it as an alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halide:
(CH3)3CCH2CH(Br)C6H5
Name the following halide according to the IUPAC system and classify it as an alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halide:
CH3CH = CHC(Br)(CH3)2
Draw the structure of major monohalo product in each of the following reactions :

The position of \[\ce{-Br}\] in the compound in \[\ce{CH3CH = CH(Br)(CH3)2}\] can be classified as ______.
Which is the correct IUPAC name for \[\begin{array}{cc}
\ce{CH3 - CH - CH2 - Br}\\
\phantom{}|\phantom{.......}\\
\phantom{}\ce{C2H5}\phantom{....}
\end{array}\]?
The reaction of toluene with chlorine in the presence of iron and in the absence of light yields ______.
Why can aryl halides not be prepared by reaction of phenol with \[\ce{HCl}\] in the presence of \[\ce{ZnCl2}\]?
Classify the following compound as a primary, secondary and tertiary halide.
1-Bromobut-2-ene
Why are haloalkanes more reactive towards nucleophilic substitution reactions than haloarenes and vinylic halides?
Name the following halide according to the IUPAC system and classify them as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl, or aryl halide:
\[\ce{CH3CH2C(CH3)2CH2I}\]
Write the structure of the following organic halogen compound.
1,4-Dibromobut-2-ene
Name the following halide according to the IUPAC system and classify it as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halide:
CH3CH2C(CH3)2CH2I
Name the following halides according to IUPAC system and classify them as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halides:
\[\ce{CH3C(C2H5)2CH2Br}\]
Give the IUPAC name of the compound.
\[\ce{CICH2 C ≡ CCH2 Br}\]
Name the following halides according to IUPAC system and classify them as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halides:
\[\ce{CH3C(Cl)(C2H5)CH2CH3}\]
Name the following halide according to IUPAC system and classify as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halide:
\[\ce{CH3C(Cl)(C2H5)CH2CH3}\]
Name the following halide according to IUPAC system and classify as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halide:
\[\ce{CH3CH2C(CH3)2CH2I}\]
