Advertisements
Advertisements
Question
Which of the carbon atoms present in the molecule given below are asymmetric?
\[\begin{array}{cc}
\phantom{}\ce{HO}\phantom{.....}\ce{OH}\phantom{..}\ce{H}\phantom{.....}\ce{O}\phantom{..}\\
\phantom{..}\backslash\phantom{.....}|\phantom{....}|\phantom{.....}//\phantom{.}\\
\ce{\overset{a}{C} - \overset{b}{C} - \overset{c}{C} - \overset{d}{C}}\\
\phantom{..}//\phantom{.....}|\phantom{....}|\phantom{....}\phantom{.}\backslash\phantom{...}\\
\phantom{}\ce{O}\phantom{......}\ce{H}\phantom{...}\ce{OH}\phantom{...}\ce{H}\phantom{}\\
\end{array}\]
Options
a, b, c, d
b, c
a, d
a, b, c
Advertisements
Solution
b, c
Explanation:
Carbon has four valencies. If a carbon atom satisfies all of its four valencies with four different groups then it is termed asymmetric/chiral carbon. In the given compound, b and c carbon are bonded to four different groups, so these are asymmetric.
APPEARS IN
RELATED QUESTIONS
Draw the structure of the major monohalo product in the following reaction:

Name the following halide according to the IUPAC system and classify it as an alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halide:
(CH3)2CHCH(Cl)CH3
Name the following halide according to the IUPAC system and classify it as an alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halide:
CH3CH(CH3)CH(Br)CH3
Name the following halide according to the IUPAC system and classify it as an alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halide:
CH3C(C2H5)2CH2Br
Name the following halide according to the IUPAC system and classify it as an alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halide:
CH3CH = C(Cl)CH2CH(CH3)2
Draw the structure of major monohalo product in each of the following reactions :

In which of the following molecules carbon atom marked with asterisk (*) is asymmetric?
(a) \[\begin{array}{cc}
\ce{H}\\
|\\
\phantom{.}\ce{C^*}\phantom{}\\
\phantom{}/\phantom{..}|\phantom{..}\backslash\phantom{}\\
\phantom{.}\ce{I}\phantom{...}\ce{Br}\phantom{..}\ce{Cl}
\end{array}\]
(b) \[\begin{array}{cc}
\ce{D}\\
|\\
\phantom{.}\ce{C^*}\phantom{}\\
\phantom{}/\phantom{..}|\phantom{..}\backslash\phantom{}\\
\phantom{.}\ce{I}\phantom{...}\ce{Br}\phantom{..}\ce{Cl}
\end{array}\]
(c) \[\begin{array}{cc}
\ce{H}\\
|\\
\phantom{.}\ce{C^*}\phantom{}\\
\phantom{}/\phantom{..}|\phantom{..}\backslash\phantom{}\\
\phantom{..}\ce{OH}\phantom{..}\ce{C2H5}\phantom{}\ce{CH3}
\end{array}\]
(d) \[\begin{array}{cc}
\ce{H}\\
|\\
\phantom{.}\ce{C^*}\phantom{}\\
\phantom{}/\phantom{..}|\phantom{..}\backslash\phantom{}\\
\phantom{..}\ce{H}\phantom{...}\ce{C2H5}\phantom{}\ce{CH3}
\end{array}\]
Name the following halides according to IUPAC system and classify them as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halides:
\[\ce{CH3CH2C(CH3)2CH2I}\]
Name the following halide according to IUPAC system and classify them as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halide:
CH3C(Cl)(C2H5)CH2CH3
Name the following halide according to IUPAC system and classify them as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halide:
\[\ce{CH3C(C2H5)2CH2Br}\]
Write the structure of the following organic halogen compound.
1,4-Dibromobut-2-ene
Name the following halide according to the IUPAC system and classify it as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl, or aryl halide:
\[\ce{CH3C(C2H5)2CH2Br}\]
Write the structure of the following organic halogen compound.
1,4-Dibromobut-2-ene
Name the following halide according to IUPAC system and classify them as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halides:
\[\ce{CH3C(C2H5)2CH2Br}\]
Name the following halides according to IUPAC system and classify them as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halides:
\[\ce{CH3CH2C(CH3)2CH2I}\]
Draw the structure of the major monohalo product in the following reaction:

The IUPAC name of the compound shown below is:
Ethylidene chloride is a/an ______.
The given compound

is an example of__________.
