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Question
What is called homologous series? Give any three of its characteristics?
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Solution
A homologous series is a group or a class of organic compounds having the same general formula and similar chemical properties in which the successive members differ by a -CH2 group.
Characteristics of homologous series:
- Each member of the series differs from the proceeding or succeeding member by one methylene group (-CH2) and hence by a molecular mass of 14 amu.
- All members of a homologous series contain the same elements and functional group.
- They are represented by a general molecular formula. Eg: Alkanes, C2H2n+2.
- The members in each homologous series show a regular gradation in their physical properties with respect to their increase in molecular mass.
- The chemical properties of the members of a homologous series are similar.
- All the members can be prepared by a common method.
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RELATED QUESTIONS
By how many carbon atoms and hydrogen atoms do any two adjacent homologues differ?
An organic compound having the molecular formula C3H6O can exist in the form of two isomers A and B having different functional groups. The isomer A is a liquid which is used as a solvent for nail polish. The isomer B is also a liquid. An aqueous solution of one of the lower homologues of B is used for preserving biological specimens in the laboratory
(a) What is compound A?
(b) Write the electron-dot structure of A.
(c) What is compound B?
(d) Write the electron-dot structure of B.
(e) Name the lower homologue of compound B which is used in preserving biological specimens.
A colourless organic liquid X of molecular formula C2H4O2 turns blue litmus to red. Another colourless organic liquid Y of molecular formula C3H6O has no action on any litmus but it is used as a nail polish remover. A yet another colourless organic liquid Z of molecular formula C2H6O has also no action on litmus but it is used in tincture of iodine.
(a) Name the liquid X. To which homologous series does it belong? Give the name of another member of this homologous series.
(b) Name the liquid Y. To which homologous series does it belong? Write the name of another member of this homologous series.
(c) Can you name an organic compound having the same molecular formula as liquid Y but which belongs to a different homologous series? What is this homologous series?
(d) Name the liquid Z. To which homologous series does it belong? Write the name of another member of this homologous series.
Give the structure of the second member of the alcohol group.
What is the difference in the molecular formula of any two adjacent homologues:
(i) In terms of molecular mass
(ii) In terms of number and kind of atoms per molecule?
The general formula of Alkane is _________________
The unsaturated hydrocarbons containing a carbon-carbon double bond are called _______.
There are different general molecular formula for all members of the homologous series.
The first member of alkyne homologous series is
Consider the following molecular formulae of carbon compounds:
(i) CH3COOH (ii) CH3OH (iii) C2H6 (iv) C3H4 (v) C4H8
- Which one of these compounds belongs to homologous series of alcohols?
- Identify the compound having triple bond between carbon-carbon atoms.
- Write the molecular formula of the first member of the homologous series to which CH3COOH belongs.
- Write the general formula of the series to which the compound C4H8 belongs.
