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प्रश्न
What is called homologous series? Give any three of its characteristics?
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उत्तर
A homologous series is a group or a class of organic compounds having the same general formula and similar chemical properties in which the successive members differ by a -CH2 group.
Characteristics of homologous series:
- Each member of the series differs from the proceeding or succeeding member by one methylene group (-CH2) and hence by a molecular mass of 14 amu.
- All members of a homologous series contain the same elements and functional group.
- They are represented by a general molecular formula. Eg: Alkanes, C2H2n+2.
- The members in each homologous series show a regular gradation in their physical properties with respect to their increase in molecular mass.
- The chemical properties of the members of a homologous series are similar.
- All the members can be prepared by a common method.
APPEARS IN
संबंधित प्रश्न
Write the name and formula of the 2nd member of homologous series having general formula CnH2n.
Complete the following table which relates to the homologous series of hydrocarbons.
| General formula | IUPAC name of the homologous series | Characteristic bond type | IUPAC name of the first member of the series |
| CnH2n−2 | (A) ______ | (B) ______ | (C) ______ |
| CnH2n+2 | (B) ______ | (E) ______ | (F) ______ |
A colourless organic liquid X of molecular formula C2H4O2 turns blue litmus to red. Another colourless organic liquid Y of molecular formula C3H6O has no action on any litmus but it is used as a nail polish remover. A yet another colourless organic liquid Z of molecular formula C2H6O has also no action on litmus but it is used in tincture of iodine.
(a) Name the liquid X. To which homologous series does it belong? Give the name of another member of this homologous series.
(b) Name the liquid Y. To which homologous series does it belong? Write the name of another member of this homologous series.
(c) Can you name an organic compound having the same molecular formula as liquid Y but which belongs to a different homologous series? What is this homologous series?
(d) Name the liquid Z. To which homologous series does it belong? Write the name of another member of this homologous series.
Succeeding members of a homologous series differ by ______.
Write names of first four homologous series of alcohols.
Copy and complete the following table, which relates to the three homologous series of hydrocarbons:
| General formula | CnH2n | CnH2n-2 | CnH2n+2 |
| IUPAC name of the homologus series | |||
| Characteristic bond type | Single bonds | ||
| IUPAC name of the first member of the series | |||
| Type of reaction with chlorine | Addition |
Write the name and formula of the fourth member of the following homologous series:
Alkyne
Complete the following table for the homologous series of alkanes.
| Name | Molecular formula | Condensed structural formula | Number of carbon atom | Number of -CH2- units | Boiling point °C |
| Methane | CH4 | CH4 | 1 | 1 | -162 |
| Ethane | C2H6 | CH3–CH3 | 2 | 2 | -88.5 |
| Propane | C3H8 | CH3–CH2–CH3 | 3 | 3 | -42 |
| Butane | C4H10 | CH3–CH2–CH2–CH3 | ______ | ______ | 0 |
| Pentane | C5H12 | CH3–CH2–CH2–CH2–CH3 | ______ | ______ | 36 |
| Hexane | C6H14 | CH3–CH2–CH2–CH2–CH2–CH3 | ______ | ______ | 69 |
Complete the following table for homologous series of alcohols.
| Name | Molecular formula | Condensed structural formula | Number of carbon atom | Number of -CH2- units | Boiling point °C |
| Methanol | CH4O | CH3-OH | 1 | 1 | 63 |
| Ethanol | C2H6O | CH3–CH2-OH | 2 | 2 | 78 |
| Propanol | C3H8O | CH3–CH2–CH2-OH | ______ | ______ | 97 |
| Butanol | C4H10O | CH3–CH2–CH2–CH2–OH | ______ | ______ | 118 |
Observe the structural formula and answer the following questions.
- Write the name of the given hydrocarbon.
- The given hydrocarbon is included in which type of hydrocarbon?
- What is the kind of compounds with the above characteristic structure called?
