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प्रश्न
What is called homologous series? Give any three of its characteristics?
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उत्तर
A homologous series is a group or a class of organic compounds having the same general formula and similar chemical properties in which the successive members differ by a -CH2 group.
Characteristics of homologous series:
- Each member of the series differs from the proceeding or succeeding member by one methylene group (-CH2) and hence by a molecular mass of 14 amu.
- All members of a homologous series contain the same elements and functional group.
- They are represented by a general molecular formula. Eg: Alkanes, C2H2n+2.
- The members in each homologous series show a regular gradation in their physical properties with respect to their increase in molecular mass.
- The chemical properties of the members of a homologous series are similar.
- All the members can be prepared by a common method.
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संबंधित प्रश्न
Write the molecular formula of first two members of homologous series having functional group -Cl.
The following vegetables are kept in a basket :
Potato, Tomato, Radish, Brinjal, Carrot, Bottle-gourd
Which two of these vegetables correctly represent the homologous structures?
(A) Carrot and Tomato
(B) Potato and Brinjal
(C) Radish and Carrot
(D) Radish and Bottle-gourd
Write the molecular formula of the third member of the homologous series of carbon compounds with general formula CnHO2n+1OH.
An organic compound having the molecular formula C3H6O can exist in the form of two isomers A and B having different functional groups. The isomer A is a liquid which is used as a solvent for nail polish. The isomer B is also a liquid. An aqueous solution of one of the lower homologues of B is used for preserving biological specimens in the laboratory
(a) What is compound A?
(b) Write the electron-dot structure of A.
(c) What is compound B?
(d) Write the electron-dot structure of B.
(e) Name the lower homologue of compound B which is used in preserving biological specimens.
Haloalkanes react with alkalies to produce alcohol. Give the equation for the preparation of the second member of the homologous series of alcohol. State under what condition the reaction occurs.
Cyclohexane : Cyclic hydrocarbon : : Isobutylene : _______
Find the odd one out and give its explanation.
Complete the following table for homologous series of Alkenes.
| Name | Molecular formula | Condensed structural formula | Number of carbon atom | Number of -CH2- units | Boiling point °C |
| Ethene | C2H4 | CH2 = CH2 | 2 | 0 | -102 |
| Propene | C3H6 | CH3–CH = CH2 | 3 | 1 | -48 |
| 1-Butene | C4H8 | CH3–CH2–CH = CH2 | ______ | ______ | -6.5 |
| 1-Pentene | C5H10 | CH3–CH2–CH2–CH = CH2 | ______ | ______ | 30 |
The first member of alkyne homologous series is
Consider the carbon compounds having following molecular formula:
(i) C2H2 (ii) C2H5 (iii) C3H7OH (iv) C2H6COOH (v) CH3CHO
- Identify which one of the above compounds, is a member of aldehyde series.
- Write the general formula of the series to which compound C2H2 belongs.
- Which one of the above compounds has triple bonds between carbon-carbon atoms?
- Write the molecular formula of the first member of the homologous series to which the compound C3H7OH belongs.
