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Karnataka Board PUCPUC Science 2nd PUC Class 12

The half-life for radioactive decay of 14C is 5730 years. An archaeological artifact containing wood had only 80% of the 14C found in a living tree. Estimate the age of the sample.

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Question

The half-life for radioactive decay of 14C is 5730 years. An archaeological artifact containing wood had only 80% of the 14C found in a living tree. Estimate the age of the sample.

Numerical
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Solution

Radioactive decay follows first-order kinetics.

∴ Decay constant (λ) = `0.693/t_(1//2)`

= `0.693/5730` year−1

[R]= 100    ...[Given]

∴ [R] = 80

t = `2.303/λ log  [R]_0/[R]`

= `2.303/((0.693/5730)) log  100/80`

= `(2.303 xx 5730)/0.693 xx 0.0969` year

= 1845 years

Hence, the age of the sample is 1845 years.

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Chapter 3: Chemical Kinetics - 'NCERT TEXT-BOOK' Exercises [Page 280]

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Nootan Chemistry [English] Class 12 ISC
Chapter 3 Chemical Kinetics
'NCERT TEXT-BOOK' Exercises | Q 4.14 | Page 280
NCERT Chemistry Part 1 and 2 [English] Class 12
Chapter 3 Chemical Kinetics
Exercises | Q 3.14 | Page 86

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