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Karnataka Board PUCPUC Science 2nd PUC Class 12

How would you account for the following: Cobalt (II) is stable in aqueous solutions, but in the presence of complexing reagents, it is easily oxidised. - Chemistry

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Question

How would you account for the following:

Cobalt (II) is stable in aqueous solutions, but in the presence of complexing reagents, it is easily oxidised.

Very Short Answer
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Solution

In the presence of complexing reagents, the crystal field stabilization energy is greater than the third ionization enthalpy of cobalt. Thus, Co (II) is easily oxidized to Co (III).

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Chapter 4: The d-block and f-block Elements - Exercises [Page 116]

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NCERT Chemistry Part 1 and 2 [English] Class 12
Chapter 4 The d-block and f-block Elements
Exercises | Q 4.21 (ii) | Page 116

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