English

Which one of the following ions is coloured?

Advertisements
Advertisements

Question

Which one of the following ions is coloured?

Options

  • Se3+

  • Ti4+

  • Zn2+

  • V2+

MCQ
Advertisements

Solution

V2+ 

Explanation:

The V2+ ion has an unpaired electron while the others have paired electrons.

So, `sqrt(2+)` is a coloured ion.

shaalaa.com
  Is there an error in this question or solution?
2016-2017 (July)

APPEARS IN

RELATED QUESTIONS

 
 
 

Complete the following chemical equations:

`(i) Cr_2O_7^(2-)+6Fe^(2+)+14H^+ ->`

`(ii) 2CrO_4^(2-)+2H^+ ->`

`(iii) 2MnO_4^-+5C_2O_4^(2-)+16H^+ ->`

 
 
 

Why +2 oxidation state of manganese is more stable?


The elements of 3d transition series are given as: Sc Ti V Cr Mn Fe Co

Answer the following: Which element is a strong oxidising agent in +3 oxidation state and why?


How is the variability in oxidation states of transition metals different from that of the non-transition metals? Illustrate with examples.


How would you account for the following:

Of the d4 species, Cr2+ is strongly reducing while manganese (III) is strongly oxidising.


Give reasons Iron has the higher enthalpy of atomization than that of copper.


The transition metals show _________ character because of the presence of unpaired· electrons and Cu+ is ____________ because of its electronic configuration is [Ar]3d10


Why do transition metal ions possess a great tendency to form complexes?


Why do transition elements show variable oxidation states ? In 3d series (Sc to Zn), which elements shows the maximum number of oxidation state and why ?


Explain why Zn2+ salts are white whereas Cu2+ salts are coloured.


Maximum oxidation state is shown by ____________.


Read the passage given below and answer the following question:

The transition metals when exposed to oxygen at low and intermediate temperatures form thin, protective oxide films of up to some thousands of Angstroms in thickness. Transition metal oxides lie between the extremes of ionic and covalent binary compounds formed by elements from the left or right side of the periodic table. They range from metallic to semiconducting and deviate by both large and small degrees from stoichiometry. Since electron bonding levels are involved, the cations exist in various valence states and hence give rise to a large number of oxides. The crystal structures are often classified by considering a cubic or hexagonal close-packed lattice of one set of ions with the other set of ions filling the octahedral or tetrahedral interstices. The actual oxide structures, however, generally show departures from such regular arrays due in part to distortions caused by packing of ions of different size and to ligand field effects. These distortions depend not only on the number of d-electrons but also on the valence and the position of the transition metal in a period or group.

In the following questions, a statement of assertion followed by a statement of reason is given. Choose the correct answer out of the following choices on the basis of the above passage.

Assertion: Cations of transition elements occur in various valence states.

Reason: Large number of oxides of transition elements are possible.


Interstitial compounds are formed when small atoms are trapped inside the crystal lattice of metals. Which of the following is not the characteristic property of interstitial compounds?


A solution of \[\ce{KMnO4}\] on reduction yields either a colourless solution or a brown precipitate or a green solution depending on pH of the solution. What different stages of the reduction do these represent and how are they carried out?


Match the properties given in Column I with the metals given in Column II.

  Column I (Property) Column II (Metal)
(i) Element with highest second
ionisation enthalpy
(a) \[\ce{Co}\]
(ii) Element with highest
third ionisation enthalpy
(b) \[\ce{Cr}\]
(iii) \[\ce{M}\] in \[\ce{M(CO)6}\] is (c) \[\ce{Cu}\]
(iv) Element with highest heat
of atomisation
(d) \[\ce{Zn}\]
    (e) \[\ce{Ni}\]

Mention the type of compounds formed when small atoms like H, C and N get trapped inside the crystal lattice of transition metals. Also give physical and chemical characteristics of these compounds.


Account for the following: 

In case of transition elements, ions of the same charge in a given series show progressive decrease in radius with increasing atomic number.


It has been observed that first ionization energy of 5 d series of transition elements are higher than that of 3d and 4d series, explain why?


Which of the following statements is not correct?


Photographic film and plates have - au essential ingredient of


Sodium this sulphate is used in photography because of its:-


Consider the following standard electrode potentials (E° in volts) in aqueous solution:

Element M3+/M M+/M
Al - 1.66 +0.55
Tl + 1.26 -0.34

Based on these data, which of the following statements is correct?


The oxidation state of Fe in [Fe(CO)5] is ______.


Assertion (A): Transition metals have high enthalpy of atomisation.

Reason (R): Greater number of unpaired electrons in transition metals results in weak metallic bonding.


Which one among the following metals of the 3d series has the lowest melting point?


Which of the following transition metals shows +1 and +2 oxidation states?


Give two similarities in the properties of Sc and Zn.


Explain the magnetic properties of d-block (or transition) elements.


For M2+/M and M3+/M2+systems, the EΘ values for some metals are as follows:

Cr2+/Cr −0.9 V
Mn2+/Mn −1.2 V
Fe2+/Fe −0.4 V
Cr3/Cr2+ −0.4 V
Mn3+/Mn2+ +1.5 V
Fe3+/Fe2+ +0.8 V

Use this data to comment upon:

The ease with which iron can be oxidised as compared to a similar process for either chromium or manganese metal.


Match List-I with List-II.

List-I List-II
A. Haber process I. Fe catalyst
B. Wacker oxidation II. PdCl2
C. Wilkinson catalyst III. [(PPh3)3RhCl]
D. Ziegler catalyst IV. TiCl4 with Al(CH3)3

Choose the correct answer from the options given below:


Share
Notifications

Englishहिंदीमराठी


      Forgot password?
Use app×