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Karnataka Board PUCPUC Science 2nd PUC Class 12

How the following conversion can be carried out? Chlorobenzene to p-nitrophenol

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Question

How the following conversion can be carried out?

Chlorobenzene to p-nitrophenol

Chemical Equations/Structures
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Solution

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Chapter 6: Haloalkanes and Haloarenes - Exercises [Page 191]

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NCERT Chemistry Part 1 and 2 [English] Class 12
Chapter 6 Haloalkanes and Haloarenes
Exercises | Q 6.19 (xv) | Page 191

RELATED QUESTIONS

What happens when \[\ce{CH3 - Br}\] is treated with KCN?


Write the final product(s) in each of the following reactions:


Give reasons:

The dipole moment of chlorobenzene is lower than that of cyclohexyl chloride.


Write the product formed on reaction of D-glucose with Br2 water.


What is Grignard reagent?


Write chemical equation in support of your answer. 
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Out of (CH3)3 C-Br and (CH3)3 C-I, which one is more reactive towards SN1 and why? 


Assertion: Presence of a nitro group at ortho or para position increases the reactivity of haloarenes towards nucleophilic substitution.

Reason: Nitro group, being an electron-withdrawing group decreases the electron density over the benzene ring.


Which of the following compounds will give racemic mixture on nucleophilic substitution by \[\ce{OH-}\] ion?

(a) \[\begin{array}{cc}
\phantom{}\ce{CH3 - CH - Br}\\
\phantom{}|\\
\phantom{....}\ce{C2H5}\phantom{}
\end{array}\]

 

(b) \[\begin{array}{cc}
\phantom{..}\ce{Br}\\
\phantom{}|\\
\phantom{}\ce{CH3 - C - CH3}\\
\phantom{}|\\
\phantom{....}\ce{C2H5}\phantom{}
\end{array}\]

 

(c) \[\begin{array}{cc}
\phantom{....}\ce{CH3 - CH - CH2Br}\\
\phantom{}|\\
\phantom{....}\ce{C2H5}\phantom{}
\end{array}\]


Arrange the following compounds in increasing order of rate of reaction towards nucleophilic substitution.

(a)
(b)
(c)

Arrange the following compounds in increasing order of rate of reaction towards nucleophilic substitution.

(a)
(b)
(c)

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(a)
(b)
(c)

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\[\ce{C6H12O6 ->[(Zymase)] A ->[NaOH][\Delta] B + CHI3}\]

The number of carbon atoms present in the product B is:


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Reason (R): C–Cl bond gets weaker due, to resonance.


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