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Find out the type of isomerism exhibited by the following pair.

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Find out the type of isomerism exhibited by the following pair.

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Solution

Tautomerism

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Chapter 14: Basic Principles of Organic Chemistry - Exercises [Page 231]

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Balbharati Chemistry [English] Standard 11 Maharashtra State Board
Chapter 14 Basic Principles of Organic Chemistry
Exercises | Q 5. D. | Page 231

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What effect does branching of an alkane chain has on its boiling point?


Find out the type of isomerism exhibited by the following pair.

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What is the relationship between the members of following pairs of structures? Are they structural or geometrical isomers or resonance contributors?

\[\begin{array}{cc}\ce{^+OH}\\||\\
\ce{H - C - OH}\end{array}\]

\[\begin{array}{cc}\ce{OH}\phantom{.}\\|\phantom{...}\\
\ce{H - C^+ - OH}\end{array}\]


Which of the following pairs are position isomers?

I. \[\begin{array}{cc}
\phantom{.......................}\ce{O}\\
\phantom{.......................}||\\
\ce{CH3 - CH2 - CH2 - CH2 - C - H}
\end{array}\]
II. \[\begin{array}{cc}
\phantom{.................}\ce{O}\\
\phantom{.................}||\\
\ce{CH3 - CH2 - CH2 - C - H}
\end{array}\]
III. \[\begin{array}{cc}
\ce{CH3 - CH2 - C - CH2 - CH3}\\
\phantom{}||\\
\phantom{}\ce{O}
\end{array}\]
IV. \[\begin{array}{cc}
\ce{CH3 - CH - CH2 - C - H}\\
\phantom{...}|\phantom{............}||\phantom{}\\
\phantom{...}\ce{CH3}\phantom{.........}\ce{O}\phantom{}
\end{array}\]

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I. \[\begin{array}{cc}
\phantom{.......................}\ce{O}\\
\phantom{.......................}||\\
\ce{CH3 - CH2 - CH2 - CH2 - C - H}
\end{array}\]
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\phantom{.................}\ce{O}\\
\phantom{.................}||\\
\ce{CH3 - CH2 - CH2 - C - H}
\end{array}\]
III. \[\begin{array}{cc}
\ce{CH3 - CH2 - C - CH2 - CH3}\\
\phantom{}||\\
\phantom{}\ce{O}
\end{array}\]
IV. \[\begin{array}{cc}
\ce{CH3 - CH - CH2 - C - H}\\
\phantom{...}|\phantom{............}||\phantom{}\\
\phantom{...}\ce{CH3}\phantom{.........}\ce{O}\phantom{}
\end{array}\]

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I. CH3 – CH2 – CH2 – CH2 – OH
II. \[\begin{array}{cc}
\ce{CH3 - CH2 - CH - CH3}\\
\phantom{.....}|\\
\phantom{.......}\ce{OH}
\end{array}\]
III. \[\begin{array}{cc}
\phantom{...}\ce{CH3}\\
\phantom{}|\\
\ce{CH3 - C - CH3}\\
\phantom{}|\\
\phantom{..}\ce{OH}
\end{array}\]
IV. \[\begin{array}{cc}
\ce{CH3 - CH - CH2 - OH}\\
|\phantom{........}\\
\ce{CH3}\phantom{......}
\end{array}\]
V. CH3 – CH2 – O – CH2 – CH3
VI. CH3 – O – CH2 – CH2 – CH3
VII. \[\begin{array}{cc}
\ce{CH3 - O - CH - CH3}\\
\phantom{...}|\\
\phantom{......}\ce{CH3}
\end{array}\]

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CH3 – S – CH2 – CH2 – CH3

And 

\[\begin{array}{cc}
\phantom{.....................}\ce{CH3}\\
\phantom{................}/\\
\phantom{}\ce{CH3 - S - CH}\\
\phantom{...............}\backslash\\
\phantom{....................}\ce{CH3}
\end{array}\]


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