English
Karnataka Board PUCPUC Science Class 11

Assertion (A): The compound cyclooctane has the following structural formula: It is cyclic and has conjugated 8π-electron system but it is not an aromatic compound. Reason (R): (4n + 2) π electrons - Chemistry

Advertisements
Advertisements

Question

Assertion (A): The compound cyclooctane has the following structural formula:

It is cyclic and has conjugated 8π-electron system but it is not an aromatic compound.

Reason (R): (4n + 2)π electrons rule does not hold good and ring is not planar.

Options

  • Both A and R are correct and R is the correct explanation of A.

  • Both A and R are correct but R is not the correct explanation of A.

  • Both A and R are not correct.

  • A is not correct but R is correct.

MCQ
Advertisements

Solution

Both A and R are correct and R is the correct explanation of A.

Explanation:

Because cyclooctatetraene is tubbed shaped

shaalaa.com
  Is there an error in this question or solution?
Chapter 13: Hydrocarbons - Multiple Choice Questions (Type - I) [Page 169]

APPEARS IN

NCERT Exemplar Chemistry [English] Class 11
Chapter 13 Hydrocarbons
Multiple Choice Questions (Type - I) | Q 44 | Page 169

RELATED QUESTIONS

Write IUPAC name of the product obtained by the ozonolysis of the following compound:

3,4-Dimethyl-hept-3-ene


Write IUPAC name of the product obtained by the ozonolysis of the following compound:

2-Ethylbut-1-ene 


Draw the cis and trans structures of hex-2-ene. Which isomer will have higher b.p. and why?


What effect does branching of an alkane chain has on its boiling point?


What is the relationship between the members of following pairs of structures? Are they structural or geometrical isomers or resonance contributors?

\[\begin{array}{cc}
\ce{D}\phantom{......}\ce{H}\\
\backslash\phantom{......}/\\
\ce{C = C}\\
\phantom{...}/\phantom{......}\backslash\phantom{...}\\\ce{H}\phantom{.......}\ce{D}
\end{array}\]

\[\begin{array}{cc}
\ce{D}\phantom{......}\ce{D}\\
\backslash\phantom{......}/\\
\ce{C = C}\\
\phantom{...}/\phantom{......}\backslash\phantom{...}\\\ce{H}\phantom{.......}\ce{H}\end{array}\]


Find out the type of isomerism exhibited by the following pair.

\[\begin{array}{cc}
\ce{CH3 - CH - CH2 - CH3 and CH3 - CH2 - O - CH2 - CH3}\\|\phantom{...........................................}\\
\ce{OH}\phantom{.........................................}\end{array}\]


Find out the type of isomerism exhibited by the following pair.


Molecular formula of the functional isomer of methyl formate is ____________.


But-1-ene and But-2-ene are examples of ____________.


Which of the following is a functional isomer of pentan-2-ol?


What is the relationship between the members of following pairs of structures? Are they structural or geometrical isomers or resonance contributors?

\[\begin{array}{cc}\ce{^+OH}\\||\\
\ce{H - C - OH}\end{array}\]

\[\begin{array}{cc}\ce{OH}\phantom{.}\\|\phantom{...}\\
\ce{H - C^+ - OH}\end{array}\]


In which of the following, functional group isomerism is not possible?


Which of the following pairs are not functional group isomers?

I. \[\begin{array}{cc}
\phantom{.......................}\ce{O}\\
\phantom{.......................}||\\
\ce{CH3 - CH2 - CH2 - CH2 - C - H}
\end{array}\]
II. \[\begin{array}{cc}
\phantom{.................}\ce{O}\\
\phantom{.................}||\\
\ce{CH3 - CH2 - CH2 - C - H}
\end{array}\]
III. \[\begin{array}{cc}
\ce{CH3 - CH2 - C - CH2 - CH3}\\
\phantom{}||\\
\phantom{}\ce{O}
\end{array}\]
IV. \[\begin{array}{cc}
\ce{CH3 - CH - CH2 - C - H}\\
\phantom{...}|\phantom{............}||\phantom{}\\
\phantom{...}\ce{CH3}\phantom{.........}\ce{O}\phantom{}
\end{array}\]

(i) II and III

(ii) II and IV

(iii) I and IV

(iv) I and II


Consider structures I to VII and answer the question:

I. CH3 – CH2 – CH2 – CH2 – OH
II. \[\begin{array}{cc}
\ce{CH3 - CH2 - CH - CH3}\\
\phantom{.....}|\\
\phantom{.......}\ce{OH}
\end{array}\]
III. \[\begin{array}{cc}
\phantom{...}\ce{CH3}\\
\phantom{}|\\
\ce{CH3 - C - CH3}\\
\phantom{}|\\
\phantom{..}\ce{OH}
\end{array}\]
IV. \[\begin{array}{cc}
\ce{CH3 - CH - CH2 - OH}\\
|\phantom{........}\\
\ce{CH3}\phantom{......}
\end{array}\]
V. CH3 – CH2 – O – CH2 – CH3
VI. CH3 – O – CH2 – CH2 – CH3
VII. \[\begin{array}{cc}
\ce{CH3 - O - CH - CH3}\\
\phantom{...}|\\
\phantom{......}\ce{CH3}
\end{array}\]

Identify the pairs of compounds which are functional group isomers.


Consider structures I to VII and answer the question:

I. CH3 – CH2 – CH2 – CH2 – OH
II. \[\begin{array}{cc}
\ce{CH3 - CH2 - CH - CH3}\\
\phantom{.....}|\\
\phantom{.......}\ce{OH}
\end{array}\]
III. \[\begin{array}{cc}
\phantom{...}\ce{CH3}\\
\phantom{}|\\
\ce{CH3 - C - CH3}\\
\phantom{}|\\
\phantom{..}\ce{OH}
\end{array}\]
IV. \[\begin{array}{cc}
\ce{CH3 - CH - CH2 - OH}\\
|\phantom{........}\\
\ce{CH3}\phantom{......}
\end{array}\]
V. CH3 – CH2 – O – CH2 – CH3
VI. CH3 – O – CH2 – CH2 – CH3
VII. \[\begin{array}{cc}
\ce{CH3 - O - CH - CH3}\\
\phantom{...}|\\
\phantom{......}\ce{CH3}
\end{array}\]

Identify the pairs of compounds that represents position isomerism.


Assertion (A): Pent- 1- ene and pent- 2- ene are position isomers.

Reason (R): Position isomers differ in the position of functional group or a substituent.


The molecules having dipole moment are:

(i) 2,2-Dimethylpropane

(ii) trans-Pent-2-ene

(iii) cis-Hex-3-ene

(iv) 2, 2, 3, 3 - Tetramethylbutane.


Tautomerism is exhibited by ______. 


The compound which shows metamerism is ______


Which type of isomerism can not be shown by benzaldoxime?


Which one of the following pairs are called position isomers?


The correct stereochemical name of


The number of acyclic structural isomers (including geometrical isomers) for pentene are ______.


Compound with molecular formula C3H6O can show ______.


Which of the following pairs of compounds are positional isomers?


Which of the following reactions will not produce a racemic product?


The number of geometrical isomers from [Co(NH3)3(NO2)3] is ______.


The total number of possible isomers of the complex compound [CuII(NH3)4][PtIICl4] is ______.


Which of the following pairs of compounds is an example of position isomerism?


Share
Notifications

Englishहिंदीमराठी


      Forgot password?
Use app×