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Find out the type of isomerism exhibited by the following pair.

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Question

Find out the type of isomerism exhibited by the following pair.

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Solution

Tautomerism

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Chapter 14: Basic Principles of Organic Chemistry - Exercises [Page 231]

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Balbharati Chemistry [English] Standard 11 Maharashtra State Board
Chapter 14 Basic Principles of Organic Chemistry
Exercises | Q 5. C. | Page 231

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What is the relationship between the members of following pairs of structures? Are they structural or geometrical isomers or resonance contributors?

\[\begin{array}{cc}
\ce{D}\phantom{......}\ce{H}\\
\backslash\phantom{......}/\\
\ce{C = C}\\
\phantom{...}/\phantom{......}\backslash\phantom{...}\\\ce{H}\phantom{.......}\ce{D}
\end{array}\]

\[\begin{array}{cc}
\ce{D}\phantom{......}\ce{D}\\
\backslash\phantom{......}/\\
\ce{C = C}\\
\phantom{...}/\phantom{......}\backslash\phantom{...}\\\ce{H}\phantom{.......}\ce{H}\end{array}\]


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\[\begin{array}{cc}\ce{^+OH}\\||\\
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I. \[\begin{array}{cc}
\phantom{.......................}\ce{O}\\
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II. \[\begin{array}{cc}
\phantom{.................}\ce{O}\\
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\ce{CH3 - CH2 - C - CH2 - CH3}\\
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\ce{CH3 - CH - CH2 - C - H}\\
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II. \[\begin{array}{cc}
\ce{CH3 - CH2 - CH - CH3}\\
\phantom{.....}|\\
\phantom{.......}\ce{OH}
\end{array}\]
III. \[\begin{array}{cc}
\phantom{...}\ce{CH3}\\
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\phantom{}|\\
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IV. \[\begin{array}{cc}
\ce{CH3 - CH - CH2 - OH}\\
|\phantom{........}\\
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V. CH3 – CH2 – O – CH2 – CH3
VI. CH3 – O – CH2 – CH2 – CH3
VII. \[\begin{array}{cc}
\ce{CH3 - O - CH - CH3}\\
\phantom{...}|\\
\phantom{......}\ce{CH3}
\end{array}\]

Identify the pairs of compounds that represents chain isomerism.


Compounds with same molecular formula but differing in their structures are said to be structural isomers. What type of structural isomerism is shown by

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\[\begin{array}{cc}
\phantom{.....................}\ce{CH3}\\
\phantom{................}/\\
\phantom{}\ce{CH3 - S - CH}\\
\phantom{...............}\backslash\\
\phantom{....................}\ce{CH3}
\end{array}\]


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