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Karnataka Board PUCPUC Science Class 11

What is the relationship between the members of following pairs of structures? Are they structural or geometrical isomers or resonance contributors?

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Question

What is the relationship between the members of following pairs of structures? Are they structural or geometrical isomers or resonance contributors?

\[\begin{array}{cc}\ce{^+OH}\\||\\
\ce{H - C - OH}\end{array}\]

\[\begin{array}{cc}\ce{OH}\phantom{.}\\|\phantom{...}\\
\ce{H - C^+ - OH}\end{array}\]

Short/Brief Note
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Solution

The given structures are canonical structures or contributing structures. They are hypothetical and individually do not represent any real molecule. Hence, the given pair represents resonance structures, called resonance isomers.

\[\begin{array}{cc}\ce{^+OH}\\||\\
\ce{H - C - OH}\end{array}\]

\[\begin{array}{cc}\ce{OH}\phantom{.}\\|\phantom{...}\\
\ce{H - C^+ - OH}\end{array}\]

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Chapter 8: Organic Chemistry - Some Basic Principles and Techniques - EXERCISES [Page 371]

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NCERT Chemistry Part 1 and 2 [English] Class 11
Chapter 8 Organic Chemistry - Some Basic Principles and Techniques
EXERCISES | Q 12.15 - (c) | Page 371

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