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Assertion (A): The compound cyclooctane has the following structural formula: It is cyclic and has conjugated 8π-electron system but it is not an aromatic compound. Reason (R): (4n + 2) π electrons

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प्रश्न

Assertion (A): The compound cyclooctane has the following structural formula:

It is cyclic and has conjugated 8π-electron system but it is not an aromatic compound.

Reason (R): (4n + 2)π electrons rule does not hold good and ring is not planar.

विकल्प

  • Both A and R are correct and R is the correct explanation of A.

  • Both A and R are correct but R is not the correct explanation of A.

  • Both A and R are not correct.

  • A is not correct but R is correct.

MCQ
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उत्तर

Both A and R are correct and R is the correct explanation of A.

Explanation:

Because cyclooctatetraene is tubbed shaped

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अध्याय 13: Hydrocarbons - Multiple Choice Questions (Type - I) [पृष्ठ १६९]

APPEARS IN

एनसीईआरटी एक्झांप्लर Chemistry Exemplar [English] Class 11
अध्याय 13 Hydrocarbons
Multiple Choice Questions (Type - I) | Q 44 | पृष्ठ १६९

संबंधित प्रश्न

Write IUPAC name of the product obtained by the ozonolysis of the following compound:

2-Ethylbut-1-ene 


Draw the cis and trans structures of hex-2-ene. Which isomer will have higher b.p. and why?


What is the relationship between the members of following pairs of structures? Are they structural or geometrical isomers or resonance contributors?

\[\begin{array}{cc}
\ce{D}\phantom{......}\ce{H}\\
\backslash\phantom{......}/\\
\ce{C = C}\\
\phantom{...}/\phantom{......}\backslash\phantom{...}\\\ce{H}\phantom{.......}\ce{D}
\end{array}\]

\[\begin{array}{cc}
\ce{D}\phantom{......}\ce{D}\\
\backslash\phantom{......}/\\
\ce{C = C}\\
\phantom{...}/\phantom{......}\backslash\phantom{...}\\\ce{H}\phantom{.......}\ce{H}\end{array}\]


Find out the type of isomerism exhibited by the following pair.

CH3 – CH2 – NH – CH2 - CH3 and CH3 - NH - CH2 - CH2 - CH3


Find out the type of isomerism exhibited by the following pair.

\[\begin{array}{cc}
\ce{CH3 - CH - CH2 - CH3 and CH3 - CH2 - O - CH2 - CH3}\\|\phantom{...........................................}\\
\ce{OH}\phantom{.........................................}\end{array}\]


Find out the type of isomerism exhibited by the following pair.


Molecular formula of the functional isomer of methyl formate is ____________.


What type(s) of isomerism is(are) shown by [Co(NH3)4Br2]Cl?


But-1-ene and But-2-ene are examples of ____________.


Which of the following is a functional isomer of pentan-2-ol?


The type of isomerism possible in 2-butene is ____________.


In which of the following, functional group isomerism is not possible?


Which of the following pairs are position isomers?

I. \[\begin{array}{cc}
\phantom{.......................}\ce{O}\\
\phantom{.......................}||\\
\ce{CH3 - CH2 - CH2 - CH2 - C - H}
\end{array}\]
II. \[\begin{array}{cc}
\phantom{.................}\ce{O}\\
\phantom{.................}||\\
\ce{CH3 - CH2 - CH2 - C - H}
\end{array}\]
III. \[\begin{array}{cc}
\ce{CH3 - CH2 - C - CH2 - CH3}\\
\phantom{}||\\
\phantom{}\ce{O}
\end{array}\]
IV. \[\begin{array}{cc}
\ce{CH3 - CH - CH2 - C - H}\\
\phantom{...}|\phantom{............}||\phantom{}\\
\phantom{...}\ce{CH3}\phantom{.........}\ce{O}\phantom{}
\end{array}\]

(i) I and II

(ii) II and III

(iii) II and IV

(iv) III and IV


Which of the following pairs are not functional group isomers?

I. \[\begin{array}{cc}
\phantom{.......................}\ce{O}\\
\phantom{.......................}||\\
\ce{CH3 - CH2 - CH2 - CH2 - C - H}
\end{array}\]
II. \[\begin{array}{cc}
\phantom{.................}\ce{O}\\
\phantom{.................}||\\
\ce{CH3 - CH2 - CH2 - C - H}
\end{array}\]
III. \[\begin{array}{cc}
\ce{CH3 - CH2 - C - CH2 - CH3}\\
\phantom{}||\\
\phantom{}\ce{O}
\end{array}\]
IV. \[\begin{array}{cc}
\ce{CH3 - CH - CH2 - C - H}\\
\phantom{...}|\phantom{............}||\phantom{}\\
\phantom{...}\ce{CH3}\phantom{.........}\ce{O}\phantom{}
\end{array}\]

(i) II and III

(ii) II and IV

(iii) I and IV

(iv) I and II


Consider structures I to VII and answer the question:

I. CH3 – CH2 – CH2 – CH2 – OH
II. \[\begin{array}{cc}
\ce{CH3 - CH2 - CH - CH3}\\
\phantom{.....}|\\
\phantom{.......}\ce{OH}
\end{array}\]
III. \[\begin{array}{cc}
\phantom{...}\ce{CH3}\\
\phantom{}|\\
\ce{CH3 - C - CH3}\\
\phantom{}|\\
\phantom{..}\ce{OH}
\end{array}\]
IV. \[\begin{array}{cc}
\ce{CH3 - CH - CH2 - OH}\\
|\phantom{........}\\
\ce{CH3}\phantom{......}
\end{array}\]
V. CH3 – CH2 – O – CH2 – CH3
VI. CH3 – O – CH2 – CH2 – CH3
VII. \[\begin{array}{cc}
\ce{CH3 - O - CH - CH3}\\
\phantom{...}|\\
\phantom{......}\ce{CH3}
\end{array}\]

Identify the pairs of compounds that represents chain isomerism.


Compounds with same molecular formula but differing in their structures are said to be structural isomers. What type of structural isomerism is shown by

CH3 – S – CH2 – CH2 – CH3

And 

\[\begin{array}{cc}
\phantom{.....................}\ce{CH3}\\
\phantom{................}/\\
\phantom{}\ce{CH3 - S - CH}\\
\phantom{...............}\backslash\\
\phantom{....................}\ce{CH3}
\end{array}\]


Assertion (A): Pent- 1- ene and pent- 2- ene are position isomers.

Reason (R): Position isomers differ in the position of functional group or a substituent.


The molecules having dipole moment are:

(i) 2,2-Dimethylpropane

(ii) trans-Pent-2-ene

(iii) cis-Hex-3-ene

(iv) 2, 2, 3, 3 - Tetramethylbutane.


Which of the following does NOT exhibit geometrical isomerism? 


Which type of isomerism can not be shown by benzaldoxime?


Acetamide is isomer of ______.


Which one of the following pairs are called position isomers?


How many structural isomers possible of the molecular formula C3H6O (excluding enol form)?


The number of acyclic structural isomers (including geometrical isomers) for pentene are ______.


Which of the following reactions will not produce a racemic product?


The number of geometrical isomers from [Co(NH3)3(NO2)3] is ______.


The total number of possible isomers of the complex compound [CuII(NH3)4][PtIICl4] is ______.


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