Advertisements
Advertisements
Question
Balance the following ionic equations.
\[\ce{MnO^{-}4 + SO^{2-}3 + H^{+} -> Mn^{2+} + SO^{2-}4 + H2O}\]
Advertisements
Solution
Dividing the equation into two half-reactions:
Oxidation half-reaction: \[\ce{SO^{2-}3 -> SO^{2-}4}\]
Reduction half-reaction: \[\ce{MnO^{-}4 -> MN^{2+}}\]
Balancing oxidation and reduction half-reactions separately as:
Oxidation half-reaction:
\[\ce{SO^{2-}3 -> SO^{2-}4}\]
\[\ce{SO^{2-}3 -> SO^{2-}4 + 2e-}\]
Since the reaction occurs in acidic medium,
\[\ce{SO^{2-}3 -> SO^{2-}4 + 2e^{-} + 2H+}\]
\[\ce{SO^{2-}3 + H2O -> SO^{2-}4 + 2H^{+} + 2e-}\] .....(i)
Reduction half-reaction:
\[\ce{MnO^{-}4 -> MN^{2+}}\]
\[\ce{MnO^{-}4 + 5e^{-} -> MN^{2+}}\]
\[\ce{MnO^{-}4 + 5e^{-} -> MN^{2+} + 4H2O}\] .....(ii)
To balance the electrons, multiply equation (i) by 5 and equation (ii) by 2 and add
\[\ce{2MO^{-}4 + 5SO^{2-}3 + 6H+ -> 2Mn^{2+} + 5SO^{2-}4 + 3H2O}\]
APPEARS IN
RELATED QUESTIONS
Calculate the oxidation number of sulphur, chromium and nitrogen in H2SO5, `"Cr"_2"O"_7^(2-)` and `"NO"_3^-`. Suggest structure of these compounds. Count for the fallacy.
Consider the reaction:
\[\ce{O3(g) + H2O2(l) → H2O(l) + 2O2(g)}\]
Why it is more appropriate to write these reaction as:
\[\ce{O3(g) + H2O2 (l) → H2O(l) + O2(g) + O2(g)}\]
Also, suggest a technique to investigate the path of the redox reactions.
How do you count for the following observations?
Though alkaline potassium permanganate and acidic potassium permanganate both are used as oxidants, yet in the manufacture of benzoic acid from toluene we use alcoholic potassium permanganate as an oxidant. Why? Write a balanced redox equation for the reaction.
Balance the following equation in the basic medium by ion-electron method and oxidation number methods and identify the oxidising agent and the reducing agent.
\[\ce{N2H4(l) + ClO^-_3 (aq) → NO(g) + Cl–(g)}\]
The Mn3+ ion is unstable in solution and undergoes disproportionation to give Mn2+, MnO2, and H+ ion. Write a balanced ionic equation for the reaction.
Balance the following reaction by oxidation number method.
\[\ce{MnO^-_{4(aq)} + Br^-_{ (aq)}->MnO2_{ (s)} + BrO^-_{3(aq)}(basic)}\]
Which of the following is INCORRECT for the following reaction?
\[\ce{2Zn_{(s)} + O2_{(g)} -> 2ZnO_{(s)}}\]
Identify coefficients 'x' and 'y' for the following reaction.
\[\ce{{x}H2O2_{(aq)} + ClO^-_{4(aq)} -> 2O2_{(g)} + ClO^-_{2(aq)} + {y}H2O_{(l)}}\]
Which of the following is a redox reaction?
Consider the reaction:
\[\ce{6 CO2(g) + 6H2O(l) → C6 H12O6(aq) + 6O2(g)}\]
Why it is more appropriate to write these reaction as:
\[\ce{6CO2(g) + 12H2O(l) → C6 H12O6(aq) + 6H2O(l) + 6O2(g)}\]
Also, suggest a technique to investigate the path of the redox reactions.
Balance the following equations by the oxidation number method.
\[\ce{I2 + NO^{-}3 -> NO2 + IO^{-}3}\]
Identify the redox reactions out of the following reactions and identify the oxidising and reducing agents in them.
\[\ce{HgCl2 (aq) + 2KI (aq) -> HgI2 (s) + 2KCl (aq)}\]
Balance the following ionic equations.
\[\ce{Cr2O^{2-}7 + Fe^{2+} + H+ -> Cr^{3+} + Fe^{3+} + H2O}\]
Balance the following ionic equations.
\[\ce{MnO^{-}4 + H^{+} + Br^{-} -> Mn^{2+} + Br2 + H2O}\]
The weight of CO is required to form Re2(CO)10 will be ______ g, from 2.50 g of Re2O7 according to given reaction
\[\ce{Re2O7 + CO -> Re2(CO)10 + CO2}\]
Atomic weight of Re = 186.2; C = 12 and O = 16.
In the reaction of oxalate with permanganate in an acidic medium, the number of electrons involved in producing one molecule of CO2 is ______.
On balancing the given redox reaction,
\[\ce{aCr2O7^2- + Bso3^2- (aq) + CH+ (aq) -> 2aCr^3+ (aq) + bSO4^2- (aq) + c(H2O(1)/2}\]
the coefficients a, b and c are found to be, respectively:
