Advertisements
Advertisements
Question
Assertion: o-Nitrophenol is less soluble in water than the m- and p-isomers.
Reason: m- and p- Nitrophenols exist as associated molecules.
Options
Assertion and reason both are correct and reason is correct explanation of assertion.
Assertion and reason both are wrong statements.
Assertion is correct statement but reason is wrong statement.
Assertion is wrong statement but reason is correct statement.
Both assertion and reason are correct statements but reason is not correct explanation of assertion.
Advertisements
Solution
Both assertion and reason are correct statements but reason is not correct explanation of assertion.
Explanation:
In o-nitrophenol there is intramolecular H-bonding.
Thus, o-nitrophenol does not form H-bond with \[\ce{H2O}\] but m-nitrophenol and p-nitrophenol form H-bonds with \[\ce{H2O}\]. Also, due to intermolecular H-bonding m-nitrophenol and p-nitrophenol exist as associated molecules.
APPEARS IN
RELATED QUESTIONS
Write the equation involved in the acetylation of Salicylic acid.
Give the structure of the product you would expect when the following alcohol reacts with HCl–ZnCl2.
Butan-1-ol
Give two reactions that show the acidic nature of phenol.
Account for the following:
o-nitrophenol is more steam volatile than p-nitrophenol.
Phenols do not react with one of the following:
Phenol is more acidic than alcohol because ____________.
Acidity of phenol is due to ____________.
In the following compounds:
The order of acidity is
Mark the correct order of decreasing acid strength of the following compounds.
| (a) |  |
| (b) |  |
| (c) |  |
| (d) |  |
| (e) |  |
Arrange the following in the increasing order of their property indicated:
4-Nitrobenzoic acid, benzoic acid, 3,4-Dinitrobenzoic acid, 4-Methoxy benzoic acid (Acid strength)
Which is the final product ‘A’ (major) in the given reaction?
Which one of the following has the lowest pKa value?
Give the structure of the product you would expect when the following alcohol reacts with HCl–ZnCl2.
2-Methylbutan-2-ol
Give the structure of the product you would expect when the following alcohol reacts with HBr.
Butan-1-ol
Give the structure of the product you would expect when the following alcohol reacts with SOCl2.
Butan-1-ol
Give the structure of the product you would expect when the following alcohol reacts with SOCl2.
2-Methylbutan-2-ol
Compare acidity of phenol with that of ethanol.
