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Answer in brief. Write reaction showing conversion of Acetaldehyde into acetaldehyde dimethyl acetal.

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Question

Answer in brief.

Write reaction showing conversion of Acetaldehyde into acetaldehyde dimethyl acetal.

Answer in Brief
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Solution

Step 1:

\[\begin{array}{cc}
\ce{H3C\phantom{..............................}}\ce{H\phantom{.........}}\\
|\phantom{..................................}|\phantom{.........}\\
\phantom{.}\ce{C = O + CH3 - OH ⇌[dry HCl][dil.HCl] H3C - C - OCH3}\\
\phantom{.}|\phantom{..................................}|\phantom{.........}\\
\phantom{..}\ce{\underset{Acetaldehyde}{H}}\phantom{......................}\ce{\underset{Hemiacetal (unstable)}{OH}}\phantom{........}
\end{array}\]

Step 2:

\[\begin{array}{cc}
\ce{H\phantom{.....................................}}\ce{H\phantom{.........}}\\
|\phantom{......................................}|\phantom{.........}\\
\ce{H3C - C - OCH3 + CH3 - OH ⇌[dry HCl][dil.HCl] H3C - C - OCH3 + H2O}\\
|\phantom{......................................}|\phantom{.........}\\
\ce{\underset{Hemiacetal (unstable)}{H}\phantom{....................}}
\ce{\underset{Acetaldehyde dimethyl acetal (stable)}{OCH3}\phantom{.}}
\end{array}\]

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Chapter 12: Aldehydes, Ketones and Carboxylic acids - Exercises [Page 281]

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Balbharati Chemistry [English] Standard 12 Maharashtra State Board
Chapter 12 Aldehydes, Ketones and Carboxylic acids
Exercises | Q 3.4 | Page 281

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