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महाराष्ट्र राज्य शिक्षण मंडळएचएससी विज्ञान (सामान्य) इयत्ता १२ वी

Answer in brief. Write reaction showing conversion of Acetaldehyde into acetaldehyde dimethyl acetal.

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प्रश्न

Answer in brief.

Write reaction showing conversion of Acetaldehyde into acetaldehyde dimethyl acetal.

थोडक्यात उत्तर
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उत्तर

Step 1:

\[\begin{array}{cc}
\ce{H3C\phantom{..............................}}\ce{H\phantom{.........}}\\
|\phantom{..................................}|\phantom{.........}\\
\phantom{.}\ce{C = O + CH3 - OH ⇌[dry HCl][dil.HCl] H3C - C - OCH3}\\
\phantom{.}|\phantom{..................................}|\phantom{.........}\\
\phantom{..}\ce{\underset{Acetaldehyde}{H}}\phantom{......................}\ce{\underset{Hemiacetal (unstable)}{OH}}\phantom{........}
\end{array}\]

Step 2:

\[\begin{array}{cc}
\ce{H\phantom{.....................................}}\ce{H\phantom{.........}}\\
|\phantom{......................................}|\phantom{.........}\\
\ce{H3C - C - OCH3 + CH3 - OH ⇌[dry HCl][dil.HCl] H3C - C - OCH3 + H2O}\\
|\phantom{......................................}|\phantom{.........}\\
\ce{\underset{Hemiacetal (unstable)}{H}\phantom{....................}}
\ce{\underset{Acetaldehyde dimethyl acetal (stable)}{OCH3}\phantom{.}}
\end{array}\]

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पाठ 12: Aldehydes, Ketones and Carboxylic acids - Exercises [पृष्ठ २८१]

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बालभारती Chemistry [English] Standard 12 Maharashtra State Board
पाठ 12 Aldehydes, Ketones and Carboxylic acids
Exercises | Q 3.4 | पृष्ठ २८१

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\[\begin{array}{cc} \phantom{...}\ce{R}\phantom{....}\ce{OR'}\phantom{}\\ \phantom{}\backslash\phantom{..}/\\ \ce{C}\\ \phantom{}/\phantom{..}\backslash\\ \phantom{...}\ce{H}\phantom{....}\ce{OR'}\phantom{} \end{array}\]


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\[\begin{array}{cc}
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||\phantom{.........}\\
\ce{O}\phantom{.........}
\end{array}\]


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Write the structure of the major product of the aldol condensation of benzaldehyde with acetone.


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