- Carbon forms many compounds, from simple ones like methane to complex ones like DNA, due to its bonding versatility.
- Catenation allows carbon to form long chains or rings by bonding with itself.
- Carbon forms single, double, and triple covalent bonds, leading to saturated and unsaturated compounds.
- Being tetravalent, carbon forms four strong covalent bonds with elements like H, O, N, and Cl.
- Isomerism increases the number of carbon compounds by allowing different structures with the same molecular formula.
Definitions [27]
Definition: Organic Compounds
All the compounds having carbon as a constituent element are called as organic compounds.
Definition: Covalent Bond
The chemical bond formed by sharing of two valence electrons between the two atoms is called covalent bond.
Define the following:
Adsorption
Adsorption is the property due to which a substance absorbs gases, liquids and solids on its surface.
Definition: Catenation
The property of self-linking of atoms of an element through covalent bonds in order to form straight chains, branched chains and cyclic chains of different sizes is known as catenation.
Definition: Tetravalency of Carbon
The characteristic of the carbon atom, by virtue of which it forms four covalent bonds, is called the tetravalency of carbon.
Define the following:
Carbonization
The process of the slow conversion of vegetable matter into carbon-rich substances is called carbonization.
Define catenation.
Carbon possesses a unique property of combining with other carbon atoms to form long chains. This property is called catenation. The chains can be straight, branched or closed.
The self-linking property of atoms of an element to form very long straight or branched chains and cyclic rings is known as catenation. This property is shown by carbon whose small size and tetravalency helps it to form large structures by self-linking.
Definition: Saturated Hydrocarbons
Saturated hydrocarbons are hydrocarbons in which the valencies of all atoms are satisfied by single bonds.
Definition: Unsaturated Compounds
The hydrocarbons that have double or triple covalent bonds between two adjacent carbon atoms are called unsaturated hydrocarbons.
OR
The carbon compounds having a double bond or triple bond between two carbon atoms are called unsaturated compounds. Ethene and ethyne are unsaturated hydrocarbons.
Definition: Alkynes
The unsaturated hydrocarbons whose structures contain a carbon-carbon triple bond are called ‘Alkynes’.
Definition: Alkanes
Saturated hydrocarbons (containing a single bond) are called ‘Alkanes’.
Definition: Hydrocarbons
Hydrocarbons are compounds that 9re made up only of carbon and hydrogen atoms.
OR
The compounds which contain carbon and hydrogen as the only two elements are called hydrocarbons.
Definition: Alkenes
The unsaturated hydrocarbons containing a carbon-carbon double bond are called ‘Alkenes’.
Definition: Aromatic Compounds
The compounds having this characteristic unit in their structure are called aromatic compounds.
Define Hydrocarbons.
The compounds which contain carbon and hydrogen as the only two elements are called hydrocarbons.
Definition: Functional Groups
"The hetero atoms or the groups of atoms containing hetero atoms are called functional groups."
Definition: Homologous Series
The same functional group substitutes for hydrogen in a carbon chain is called a homologous series.
OR
A homologous series is a group of organic compounds having similar structure and similar chemical properties in which the successive compounds differ by a CH2 group.
OR
The series of compounds formed by joining the same functional group in the place of a particular hydrogen atom on the chains having sequentially increasing length is called homologous series.
Define Homologous series.
A series of compounds with similar chemical properties, in which members differ from one another by an additional CH2 group, is called a homologous series.
Definition: Nomenclature
Nomenclature is the system of assignment of names to organic compounds.
Define redox reaction.
Redox reactions are those in which reduction and oxidation both takes place simultaneously i.e. one substance is reduced while the other gets oxidised.
Definition: Oxidants or Oxidising Agents
Chemical substances which bring about an oxidation reaction by making oxygen available are called oxidants or oxidizing agents.
OR
Substances that can give oxygen to other substances are called oxidants or oxidizing agents.
Definition: Oxidation Reaction
The chemical reaction in which a reactant combines with oxygen or loses hydrogen to form the product is called oxidation reaction.
Define reduction.
Those reactions in which hydrogen combines with a substance or oxygen is removed from a substance, are known as reduction reactions.
Example: \[\ce{2HgO->[heat]2Hg +O2}\]
Define corrosion.
When the surface of a metal is attacked by air, moisture or any other substance around it, the metal is said to corrode and the phenomenon is known as corrosion.
Corrosion is an electrochemical process in which a metal is oxidised to a metal oxide or another salt of the metal by losing electrons to oxygen or another electronegative element, forming a coating on the metal surface.
Define an oxidation reaction.
The chemical reaction in which reactants gain oxygen to form the corresponding oxide. Also, A chemical reaction in which reactants lose hydrogen to form a product is called oxidation.
Example: \[\ce{H2S + Cl -> 2HCl + S}\]
Define oxidation number.
The oxidation number of an element is defined as the formal charge that an atom of that element appears to have when electrons are counted.
Definition: Substitution Reaction
The reaction in which the place of one type of atom/group in a reactant is taken by another atom/group of atoms is called a substitution reaction.
Chemica Equations [1]
Chemical Reaction: Chlorination of Methane
- \[\mathrm{CH}_4+\mathrm{Cl}_2\xrightarrow{\mathrm{Sunlight}}\mathrm{CH}_3-\mathrm{Cl}+\mathrm{HCl}\]
→ 1 hydrogen replaced → methyl chloride - \[\mathrm{CH}_3\mathrm{Cl}+\mathrm{Cl}_2\xrightarrow{\mathrm{Sunlight}}\mathrm{CH}_2\mathrm{Cl}_2+\mathrm{HCl}\]
→ 2 hydrogens replaced → methylene chloride - \[\mathrm{CH}_2\mathrm{Cl}_2+\mathrm{Cl}_2\xrightarrow{\mathrm{Sunlight}}\mathrm{CHCl}_3+\mathrm{HCl}\]
→ 3 hydrogens replaced → chloroform - \[\mathrm{CHCl}_3+\mathrm{Cl}_2\xrightarrow{\mathrm{Sunlight}}\mathrm{CCl}_4+\mathrm{HCl}\]
→ All 4 hydrogens replaced → carbon tetrachloride
Key Points
Key Points: Bonds in Carbon Compounds
- Organic compounds are mainly carbon compounds, except CO₂, CO, carbonates, bicarbonates, and carbides, which are inorganic.
- Carbon compounds have low melting and boiling points (generally below 300 °C) due to weak intermolecular forces.
- Most carbon compounds do not conduct electricity, showing the absence of ionic bonds.
- Carbon forms covalent bonds by sharing electrons to achieve a stable noble gas configuration.
- Carbon can form single, double, and triple covalent bonds, allowing the formation of many compounds like CH₄, O₂, and N₂.
Key Points: Carbon: A Versatile Element
Key Points: Hydrocarbons
- Hydrocarbons contain only carbon and hydrogen atoms and are the basic type of organic compounds.
- Saturated hydrocarbons have single bonds (e.g. methane, ethane, propane).
- Unsaturated hydrocarbons have double or triple bonds (e.g. ethene, ethyne).
- To draw structures, join the carbon atoms first, then add hydrogen atoms to complete 4 bonds per carbon.
- Ethene has a double bond, and ethyne has a triple bond between carbon atoms.
Key Points: Straight chains, Branched chains, and Rings of Carbon atoms
- Carbon compounds can have straight, branched, or ring chains of carbon atoms.
- Isomers have the same formula but different structures (e.g., butane).
- Crude oil is a mix of hydrocarbons; fuels like LPG and petrol are separated by fractional distillation.
- Saturated hydrocarbons have single bonds, while unsaturated ones have double or triple bonds.
- Aromatic compounds, such as benzene, have rings with alternating double bonds.
Key Points: Homologous Series
Key points: Nomenclature of Carbon Compounds
- The IUPAC system provides a unique, systematic way to name carbon compounds based on structure, replacing confusing common names.
- An IUPAC name has three parts: prefix, parent, and suffix, reflecting the carbon chain and functional group.
- The parent name is based on the longest carbon chain, and its ending changes to –ane, –ene, or –yne depending on the number of bonds.
- Functional groups are shown as prefixes or suffixes, and the chain is numbered to give them the lowest possible number.
- If the suffix begins with a vowel, the final ‘e’ in the parent alkane name is dropped (e.g., propane → propanone).
Key Points: Combustion
Key Points: Oxidation
Key Points: Addition Reaction
- Unsaturated compounds undergo addition reactions with hydrogen in the presence of a nickel or platinum catalyst to form saturated compounds.
- Hydrogenation of vegetable oils with a nickel catalyst converts unsaturated fats into saturated fats, such as Vanaspati ghee.
- Unsaturated fats with double bonds are healthier, whereas saturated fats are considered harmful to health.
Key Points: Ethanol
- Ethanol is a colourless liquid with a boiling point of 78 °C, soluble in water, and used in medicines, drinks, and as a clean-burning fuel (e.g., gasohol).
- Ethanol reacts with sodium to form sodium ethoxide and hydrogen gas is evolved.
- When heated with concentrated H₂SO₄ at 170 °C, ethanol undergoes dehydration to form ethene, an unsaturated compound.
- Methanol is highly poisonous, and industrial ethanol is made unfit for drinking by mixing methanol and adding a blue dye (denatured spirit).
Key Points: Ethanoic Acid
- Ethanoic acid (acetic acid) is a carboxylic acid; its 5–8% aqueous solution is vinegar, and it shows acidic nature by turning blue litmus red.
- Pure ethanoic acid freezes at 17 °C (290 K), so it is called glacial acetic acid.
- Being a weak acid, ethanoic acid is not completely ionised in aqueous solution.
- Ethanoic acid reacts with bases, carbonates, and bicarbonates to form a salt, water, and CO₂ (CO₂ turns lime water milky).
- It reacts with ethanol in the presence of conc. H₂SO₄ to form an ester (ethyl ethanoate) with a sweet smell (esterification).
Key Points: Macromolecules and Polymers
- Macromolecules are large molecules made of many atoms; they include natural and manmade polymers.
- Natural macromolecules like starch, cellulose, proteins, and DNA are essential for life.
- Man-made macromolecules such as plastics, fibres, and rubber are used in daily life.
- Polymers are made by repeating small units called monomers through polymerization.
- Properties of polymers depend on the type of monomers and how they are arranged (straight, branched, or cross-linked).
Important Questions [21]
- Complete the following flow chart:
- Identify the hydrocarbon from the given electron-dot structure: H....HH..A∙∙..C∙.∙∙.∙..A∙∙..C∙.∙∙.∙..A∙∙..HH....H
- Draw electron dot structure for the following: H..H|...|H−C−C−H|...|H..H
- Identify saturated and unsaturated hydrocarbons from the given structural formula: H..H|...|H−C−C−H|...|H..H ..H........H..∖....../C=C/......∖H........H (1) (2)
- Draw electron dot structure for the following: ..H........H..∖....../C=C/......∖H........H
- ______ is the functional group of carboxylic acid.
- Define Hydrocarbons.
- Complete the correlation: Alkene : C = C :: Alkyne: _______.
- Write names of first four homologous series of alcohols.
- Define Homologous series.
- Distinguish Between Oxidation and Reduction.
- Give scientific reason. It is reccommended to use air tight container for storing oil for long time.
- Identify the type of chemical reaction given below: 2Mg+OA2⟶2MgO
- Define an oxidation reaction.
- Write the Chemical Formula of Rust.
- What is Meant by Rust?
- Define ‘Redox Reaction’. Give One Example.
- Define corrosion.
- The Chemical Formula for Rust is
- Corrosion Can Be Prevented by Using Anti-rust Solution.
- Observe the diagram given below and answer the questions: Name the reactants in this reaction. Which gas comes out as effervescence in the bigger test tube? What is the colour change in the lim
Concepts [14]
- Bonds in Carbon Compounds
- Carbon: A Versatile Element
- Hydrocarbons
- Straight chains, Branched chains, and Rings of Carbon atoms
- Functional Groups in Carbon Compounds
- Homologous Series
- Nomenclature
- Chemical Properties of Carbon Compounds > Combustion
- Chemical Properties of Carbon Compounds > Oxidation
- Chemical Properties of Carbon Compounds > Addition Reaction
- Chemical Properties of Carbon Compounds > Substitution Reaction
- Ethanol
- Ethanoic Acid
- Macromolecules and Polymers
