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प्रश्न
Write electronic configurations of \[\ce{Fe, Fe2+, Fe3+}\].
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उत्तर
| Species | Orbital notation |
| \[\ce{Fe}\] | 1s2 2s2 2p6 3s2 3p6 4s2 3d6 OR [Ar] 4s23d6 |
| \[\ce{Fe2+}\] | 1s2 2s2 2p6 3s2 3p6 3d6 OR [Ar] 3d6 |
| \[\ce{Fe3+}\] | 1s2 2s2 2p6 3s2 3p6 3d5 OR [Ar] 3d5 |
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संबंधित प्रश्न
Choose the correct option.
“No two electrons in the same atoms can have identical set of four quantum numbers”. This statement is known as -
Give the names of quantum numbers.
State and explain Pauli’s exclusion principle.
State Hund’s rule of maximum multiplicity with a suitable example.
State the order of filling atomic orbitals following Aufbau principle.
Write condensed orbital notation of electronic configuration of the following element:
Oxygen (Z = 8)
Draw shapes of 2p orbitals.
The electronic configuration of oxygen is written as 1s2 2s2 \[\ce{2p^2_{{x}}}\] \[\ce{2p^1_{{y}}}\] \[\ce{2p^1_{{z}}}\] and not as 1s2 2s2 \[\ce{2p^2_{{x}}}\], \[\ce{2p^2_{{y}}}\] \[\ce{2p^0_{{z}}}\], Explain.
Using the concept of quantum numbers, calculate the maximum numbers of electrons present in the ‘M’ shell. Give their distribution in shells, subshells, and orbitals.
Indicate the number of unpaired electrons in \[\ce{Si}\] (Z = 14).
Indicate the number of unpaired electron in:
Cr (Z = 24)
Which mineral among the following contains vanadium in it?
Which of the following has a greater number of electrons than neutrons?
(Mass number of Mg, C, O and Na is 24, 12, 16 and 23 respectively).
Total number of orbitals associated with third shell will be ______.
Orbital angular momentum depends on ______.
The pair of ions having same electronic configuration is ______.
Which of the following sets of quantum numbers are correct?
| `n` | `l` | `m_l` | |
| (i) | 1 | 1 | +2 |
| (ii) | 2 | 1 | +1 |
| (iii) | 3 | 2 | –2 |
| (iv) | 3 | 4 | –2 |
Which of the following orbitals are degenerate?
3dxy, 4dxy 3dz2, 3dyz, 4dyz, 4dz2
Calculate the total number of angular nodes and radial nodes present in 3p orbital.
The arrangement of orbitals on the basis of energy is based upon their (n + l) value. Lower the value of (n + l), lower is the energy. For orbitals having same values of (n + l), the orbital with lower value of n will have lower energy.
Based upon the above information, arrange the following orbitals in the increasing order of energy.
4s, 3s, 3p, 4d
The arrangement of orbitals on the basis of energy is based upon their (n + l) value. Lower the value of (n + l), lower is the energy. For orbitals having same values of (n + l), the orbital with lower value of n will have lower energy.
Based upon the above information, arrange the following orbitals in the increasing order of energy.
5p, 4d, 5d, 4f, 6s
The arrangement of orbitals on the basis of energy is based upon their (n + l) value. Lower the value of (n + l), lower is the energy. For orbitals having same values of (n + l), the orbital with lower value of n will have lower energy.
Based upon the above information, solve the questions given below:
Which of the following orbitals has the lowest energy?
4d, 4f, 5s, 5p
The electronic configuration of valence shell of Cu is 3d104s1 and not 3d94s2. How is this configuration explained?
What is the difference between the terms orbit and orbital?
Match the quantum numbers with the information provided by these.
| Quantum number | Information provided |
| (i) Principal quantum number | (a) orientation of the orbital |
| (ii) Azimuthal quantum number | (b) energy and size of orbital |
| (iii) Magnetic quantum number | (c) spin of electron |
| (iv) Spin quantum number | (d) shape of the orbital |
Match species given in Column I with the electronic configuration given in Column II.
| Column I | Column II |
| (i) \[\ce{Cr}\] | (a) [Ar]3d84s0 |
| (ii) \[\ce{Fe^{2+}}\] | (b) [Ar]3d104s1 |
| (iii) \[\ce{Ni^{2+}}\] | (c) [Ar]3d64s0 |
| (iv) \[\ce{Cu}\] | (d) [Ar] 3d54s1 |
| (e) [Ar]3d64s2 |
In assigning R - S configuration, which among the following groups has highest priority?
Which of the following element do not follow Aufbau principle?
