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Why is FeO (s) not formed in stoichiometric composition? - Chemistry

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प्रश्न

Why is FeO (s) not formed in stoichiometric composition?

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उत्तर

In the crystals of FeO, some of the Fe2+ cations are replaced by Fe3+ ions. Three Fe2+ ions are replaced by two Fe3+ ions to make up for the loss of positive charge. Eventually there would be less amount of metal as compared to stoichiometric proportion.

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पाठ 1: Solid States - Exercises [पृष्ठ १०]

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एनसीईआरटी एक्झांप्लर Chemistry [English] Class 12
पाठ 1 Solid States
Exercises | Q III. 58. | पृष्ठ १०

संबंधित प्रश्‍न

Explain the following term with a suitable example:

Interstitials


Out of NaCl and AgCl, which one shows Frenkel defect and why? 


Answer the following question.
What type of stoichiometric defect is shown by ZnS and why?


Ionic solids containing large differences in sizes of ions show ____________.


Defect shown by non-ionic solids is ____________.


The radius of Cs+ is 169 pm and Cl is 181 pm. The radius ratio is ____________.


The following diagram shows:


Schottky defect defines imperfection in the lattice structure of ____________.


Alkali halids do not show Frenkel defect because ____________.


Silver halides generally show:


What is the effect of Frenkel defect on the density of ionic solids?


Cations are present in the interstitial sites in ______.


Which of the following defects is also known as dislocation defect?


Which of the following statements are not true?

(i) Vacancy defect results in a decrease in the density of the substance.

(ii) Interstitial defects results in an increase in the density of the substance.

(iii) Impurity defect has no effect on the density of the substance.

(iv) Frankel defect results in an increase in the density of the substance.


Frenkel defect is also known as:

(i) stoichiometric defect

(ii) dislocation defect

(iii) impurity defect

(iv) non-stoichiometric defect


Which of the following defects decrease the density?

(i) Interstitial defect

(ii) Vacancy defect

(iii) Frankel defect

(iv) Schottky defect


Given below are two statements, one is labelled as Assertion (A) and the other is labelled as Reason (R):

Assertion: In any ionic solid (MX) with Schottky defects, the number of positive and negative ions are same.

Reason: Equal number of cation and anion vacancies are present.


If NaCl is doped with 10–4 mole percent of SrCl2 the concentration of cation vacancies will be


Which type of ‘defect’ has the presence of cations in the interstitial sites?


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