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प्रश्न
Examine the given defective crystal:
Answer the following questions :
(i) What type of stoichiometric defect is shown by the crystal?
(ii) How is the density of the crystal affected by this defect?
(iii) What type of ionic substances show such defect?
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उत्तर
(i) Schottky defect is shown by the mentioned crystal, as equal number of cations and anions are missing in the crystal lattice.
(ii) This defect leads to decrease in density, as equal number of the cations and anions are missing from the crystal lattice.
(iii) This kind of defect is shown by those ionic substance in which the cations and anions are of almost similar sizes.
Examples: NaCl, KCl and CsCl.
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संबंधित प्रश्न
non-stoichiometric defects?
Ionic solids containing large differences in sizes of ions show ____________.
Defects in solids can be studied using
What is the effect of Frenkel defect on the density of ionic solids?
Cations are present in the interstitial sites in ______.
Schottky defect is observed in crystals when ______.
Which of the following point defects are shown by AgBr(s) crystals?
- Schottky defect
- Frenkel defect
- Metal excess defect
- Metal deficiency defect
Frenkel defect is also known as:
(i) stoichiometric defect
(ii) dislocation defect
(iii) impurity defect
(iv) non-stoichiometric defect
Match the defects given in Column I with the statements in given Column II.
| Column I | Column II |
| (i) Simple vacancy defect | (a) shown by non-ionic solids and increases density of the solid. |
| (ii) Simple interstitial defect | (b) shown by ionic solids and decreases density of the solid. |
| (iii) Frenkel defect | (c) shown by non ionic solids and density of the solid decreases. |
| (iv) Schottky defect | (d) shown by ionic solids and density of the solid remains the same. |
Given below are two statements:
Statements I: Frenkel defects are vacancy as well as interstitial defects.
Statements II: Frenkel defect leads of colour in ionic solids due to the presence of F-centers.
Choose the most appropriate answer for the statements from the options given below:
