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प्रश्न
Examine the given defective crystal:
Answer the following questions :
(i) What type of stoichiometric defect is shown by the crystal?
(ii) How is the density of the crystal affected by this defect?
(iii) What type of ionic substances show such defect?
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उत्तर
(i) Schottky defect is shown by the mentioned crystal, as equal number of cations and anions are missing in the crystal lattice.
(ii) This defect leads to decrease in density, as equal number of the cations and anions are missing from the crystal lattice.
(iii) This kind of defect is shown by those ionic substance in which the cations and anions are of almost similar sizes.
Examples: NaCl, KCl and CsCl.
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संबंधित प्रश्न
Explain the following term with suitable examples:
Frenkel defect
Explain the following term with a suitable example:
Interstitials
Answer the following question.
What type of stoichiometric defect is shown by ZnS and why?
Frenkel defects are not found in alkali metal halides because ____________.
The radius of Cs+ is 169 pm and Cl− is 181 pm. The radius ratio is ____________.
Assertion: No compound has both Schottky and Frenkel defects.
Reason: Both defects change the density of the solid.
Alkali halids do not show Frenkel defect because ____________.
Frenkel defect is also known as:
(i) stoichiometric defect
(ii) dislocation defect
(iii) impurity defect
(iv) non-stoichiometric defect
Which of the following defects decrease the density?
(i) Interstitial defect
(ii) Vacancy defect
(iii) Frankel defect
(iv) Schottky defect
Given below are two statements:
Statements I: Frenkel defects are vacancy as well as interstitial defects.
Statements II: Frenkel defect leads of colour in ionic solids due to the presence of F-centers.
Choose the most appropriate answer for the statements from the options given below:
