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Why is FeO (s) not formed in stoichiometric composition? - Chemistry

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प्रश्न

Why is FeO (s) not formed in stoichiometric composition?

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उत्तर

In the crystals of FeO, some of the Fe2+ cations are replaced by Fe3+ ions. Three Fe2+ ions are replaced by two Fe3+ ions to make up for the loss of positive charge. Eventually there would be less amount of metal as compared to stoichiometric proportion.

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अध्याय 1: Solid States - Exercises [पृष्ठ १०]

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एनसीईआरटी एक्झांप्लर Chemistry [English] Class 12
अध्याय 1 Solid States
Exercises | Q III. 58. | पृष्ठ १०

संबंधित प्रश्न

Explain the following term with a suitable example:

Interstitials


Examine the given defective crystal:

Answer the following questions :
(i) What type of stoichiometric defect is shown by the crystal?
(ii) How is the density of the crystal affected by this defect?
(iii) What type of ionic substances show such defect?


What type of defect is shown by NaCl in 
 stoichiometric defects, and


 non-stoichiometric defects?


Dislocation defect is also known as ____________.


The radius of Cs+ is 169 pm and Cl is 181 pm. The radius ratio is ____________.


Type of stoichiometric defect shown by ZnS is ____________.


Type of stoichiometric defect shown by AgBr is ____________.


The following diagram shows:


Schottky defect defines imperfection in the lattice structure of ____________.


Which of the following crystals does not exhibit Frenkel defect?


What is the effect of Frenkel defect on the density of ionic solids?


Which of the following statements are not true?

(i) Vacancy defect results in a decrease in the density of the substance.

(ii) Interstitial defects results in an increase in the density of the substance.

(iii) Impurity defect has no effect on the density of the substance.

(iv) Frankel defect results in an increase in the density of the substance.


Frenkel defect is also known as:

(i) stoichiometric defect

(ii) dislocation defect

(iii) impurity defect

(iv) non-stoichiometric defect


Which of the following defects decrease the density?

(i) Interstitial defect

(ii) Vacancy defect

(iii) Frankel defect

(iv) Schottky defect


Schottky defect is noticed in ______


Which type of ‘defect’ has the presence of cations in the interstitial sites?


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