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Question
Why is FeO (s) not formed in stoichiometric composition?
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Solution
In the crystals of FeO, some of the Fe2+ cations are replaced by Fe3+ ions. Three Fe2+ ions are replaced by two Fe3+ ions to make up for the loss of positive charge. Eventually there would be less amount of metal as compared to stoichiometric proportion.
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RELATED QUESTIONS
Explain the following term with suitable examples:
Frenkel defect
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(ii) How is the density of the crystal affected by this defect?
(iii) What type of ionic substances show such defect?
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Frenkel defect is also known as:
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(ii) dislocation defect
(iii) impurity defect
(iv) non-stoichiometric defect
Given below are two statements, one is labelled as Assertion (A) and the other is labelled as Reason (R):
Assertion: In any ionic solid (MX) with Schottky defects, the number of positive and negative ions are same.
Reason: Equal number of cation and anion vacancies are present.
If NaCl is doped with 10–4 mole percent of SrCl2 the concentration of cation vacancies will be
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Statements II: Frenkel defect leads of colour in ionic solids due to the presence of F-centers.
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Which type of ‘defect’ has the presence of cations in the interstitial sites?
