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प्रश्न
Out of NaCl and AgCl, which one shows Frenkel defect and why?
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उत्तर
The Frenkel defect is that in which one smaller ion (usually cations) move from its lattice position to an interstitial site i.e. a tetrahedral octahedral hole to form a vacancy in the lattice. Of course, AgCl has the defect because the size of AgCl is intermediate and since the size of Ag+ cation is smaller than chloride ion so it can move to interstitial spaces causing Frenkel to defect while in NaCl (alkali metal halide) they have a larger size of cations which do not fit into voids and so the defect is not shown by the alkali metal halides.
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संबंधित प्रश्न
Explain the following term with a suitable example:
Interstitials
Examine the given defective crystal:
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(i) What type of stoichiometric defect is shown by the crystal?
(ii) How is the density of the crystal affected by this defect?
(iii) What type of ionic substances show such defect?
Answer the following question.
What type of stoichiometric defect is shown by ZnS and why?
The radius of Cs+ is 169 pm and Cl− is 181 pm. The radius ratio is ____________.
In a Schottky defect ____________.
Schottky defect is observed in crystals when ______.
Which of the following defects is also known as dislocation defect?
Given below are two statements, one is labelled as Assertion (A) and the other is labelled as Reason (R):
Assertion: In any ionic solid (MX) with Schottky defects, the number of positive and negative ions are same.
Reason: Equal number of cation and anion vacancies are present.
Schottky defect is noticed in ______
The incorrect statement about the imperfections in solids is ______.
