Advertisements
Advertisements
प्रश्न
When a photon is emitted from an atom, the atom recoils. The kinetic energy of recoil and the energy of the photon come from the difference in energies between the states involved in the transition. Suppose, a hydrogen atom changes its state from n = 3 to n = 2. Calculate the fractional change in the wavelength of light emitted, due to the recoil.
Advertisements
उत्तर
Difference in energy in the transition from n = 3 to n = 2 is 1.89 eV ( = E).
If all this energy is used up in emitting a photon (i.e. recoil energy is zero).
Then,
`E = (hc)/lamda`
`rArr lamda = (hc)/E` ..........(i)
If difference of energy is used up in emitting a photon and recoil of atom, then let ER be the recoil energy of atom.
`E = (hc)/lamda + E_R`
`rArr lamda ' = (hc)/(E - E_R)` ............(ii)
Fractional change in the wavelength is given as,
`(Delta lamda)/lamda = (lamda'-lamda)/lamda`
`rArr (Deltalamda)/lamda = 1/lamda((hc)/(E-E_R ) - (hc)/E)`
`rArr (Delta lamda)/(lamda)=E/(hc) (hcE_R)/(E(E-E_R)) (therefore lamda = (hc)/E)`
`rArr (Deltalamda)/lamda = ((E_R)/(E- E_R))`
APPEARS IN
संबंधित प्रश्न
If Bohr’s quantisation postulate (angular momentum = nh/2π) is a basic law of nature, it should be equally valid for the case of planetary motion also. Why then do we never speak of quantisation of orbits of planets around the sun?
Find the wavelength of the electron orbiting in the first excited state in hydrogen atom.
In which of the following transitions will the wavelength be minimum?
In which of the following systems will the radius of the first orbit (n = 1) be minimum?
As one considers orbits with higher values of n in a hydrogen atom, the electric potential energy of the atom
A hydrogen atom in ground state absorbs 10.2 eV of energy. The orbital angular momentum of the electron is increased by
Let An be the area enclosed by the nth orbit in a hydrogen atom. The graph of ln (An/A1) against ln(n)
(a) will pass through the origin
(b) will be a straight line with slope 4
(c) will be a monotonically increasing nonlinear curve
(d) will be a circle
Find the radius and energy of a He+ ion in the states (a) n = 1, (b) n = 4 and (c) n = 10.
(a) Find the first excitation potential of He+ ion. (b) Find the ionization potential of Li++ion.
A group of hydrogen atoms are prepared in n = 4 states. List the wavelength that are emitted as the atoms make transitions and return to n = 2 states.
Whenever a photon is emitted by hydrogen in Balmer series, it is followed by another photon in Lyman series. What wavelength does this latter photon correspond to?
What is the energy of a hydrogen atom in the first excited state if the potential energy is taken to be zero in the ground state?
A gas of hydrogen-like ions is prepared in a particular excited state A. It emits photons having wavelength equal to the wavelength of the first line of the Lyman series together with photons of five other wavelengths. Identify the gas and find the principal quantum number of the state A.
Find the temperature at which the average thermal kinetic energy is equal to the energy needed to take a hydrogen atom from its ground state to n = 3 state. Hydrogen can now emit red light of wavelength 653.1 nm. Because of Maxwellian distribution of speeds, a hydrogen sample emits red light at temperatures much lower than that obtained from this problem. Assume that hydrogen molecules dissociate into atoms.
Average lifetime of a hydrogen atom excited to n = 2 state is 10−8 s. Find the number of revolutions made by the electron on the average before it jumps to the ground state.
A hydrogen atom in ground state absorbs a photon of ultraviolet radiation of wavelength 50 nm. Assuming that the entire photon energy is taken up by the electron with what kinetic energy will the electron be ejected?
Electrons are emitted from an electron gun at almost zero velocity and are accelerated by an electric field E through a distance of 1.0 m. The electrons are now scattered by an atomic hydrogen sample in ground state. What should be the minimum value of E so that red light of wavelength 656.3 nm may be emitted by the hydrogen?
The Balmer series for the H-atom can be observed ______.
- if we measure the frequencies of light emitted when an excited atom falls to the ground state.
- if we measure the frequencies of light emitted due to transitions between excited states and the first excited state.
- in any transition in a H-atom.
- as a sequence of frequencies with the higher frequencies getting closely packed.
In the Auger process an atom makes a transition to a lower state without emitting a photon. The excess energy is transferred to an outer electron which may be ejected by the atom. (This is called an Auger electron). Assuming the nucleus to be massive, calculate the kinetic energy of an n = 4 Auger electron emitted by Chromium by absorbing the energy from a n = 2 to n = 1 transition.
