Advertisements
Advertisements
प्रश्न
The average kinetic energy of molecules in a gas at temperature T is 1.5 kT. Find the temperature at which the average kinetic energy of the molecules of hydrogen equals the binding energy of its atoms. Will hydrogen remain in molecular from at this temperature? Take k = 8.62 × 10−5 eV K−1.
Advertisements
उत्तर
Average kinetic energy (K) of the molecules in a gas at temperature (T) is given by
K = `3/2 kT`
Here,
k = 8.62 × 10−5 eVK−1
T = Temperature of gas
The binding energy of hydrogen atom is 13.6 eV.
According to the question,
Average kinetic energy of hydrogen molecules = Binding energy of hydrogen atom
∴ 1.5 kT = 13.6
⇒ 1.5 × 8.62 × 10−5 × T = 13.6
`rArr T = (13.6)/(1.5xx8.62xx10^-5)`
No, it is impossible for hydrogen to remain in molecular state at such a high temperature.
APPEARS IN
संबंधित प्रश्न
A 12.5 eV electron beam is used to bombard gaseous hydrogen at room temperature. What series of wavelengths will be emitted?
If Bohr’s quantisation postulate (angular momentum = nh/2π) is a basic law of nature, it should be equally valid for the case of planetary motion also. Why then do we never speak of quantisation of orbits of planets around the sun?
Find the wavelength of the electron orbiting in the first excited state in hydrogen atom.
When white radiation is passed through a sample of hydrogen gas at room temperature, absorption lines are observed in Lyman series only. Explain.
What will be the energy corresponding to the first excited state of a hydrogen atom if the potential energy of the atom is taken to be 10 eV when the electron is widely separated from the proton? Can we still write En = E1/n2, or rn = a0 n2?
In which of the following systems will the radius of the first orbit (n = 1) be minimum?
Which of the following curves may represent the speed of the electron in a hydrogen atom as a function of trincipal quantum number n?
Let An be the area enclosed by the nth orbit in a hydrogen atom. The graph of ln (An/A1) against ln(n)
(a) will pass through the origin
(b) will be a straight line with slope 4
(c) will be a monotonically increasing nonlinear curve
(d) will be a circle
Ionization energy of a hydrogen-like ion A is greater than that of another hydrogen-like ion B. Let r, u, E and L represent the radius of the orbit, speed of the electron, energy of the atom and orbital angular momentum of the electron respectively. In ground state
Find the binding energy of a hydrogen atom in the state n = 2.
Find the radius and energy of a He+ ion in the states (a) n = 1, (b) n = 4 and (c) n = 10.
Find the maximum angular speed of the electron of a hydrogen atom in a stationary orbit.
Suppose, in certain conditions only those transitions are allowed to hydrogen atoms in which the principal quantum number n changes by 2. (a) Find the smallest wavelength emitted by hydrogen. (b) List the wavelength emitted by hydrogen in the visible range (380 nm to 780 nm).
Average lifetime of a hydrogen atom excited to n = 2 state is 10−8 s. Find the number of revolutions made by the electron on the average before it jumps to the ground state.
A hydrogen atom moving at speed υ collides with another hydrogen atom kept at rest. Find the minimum value of υ for which one of the atoms may get ionized.
The mass of a hydrogen atom = 1.67 × 10−27 kg.
When a photon is emitted from an atom, the atom recoils. The kinetic energy of recoil and the energy of the photon come from the difference in energies between the states involved in the transition. Suppose, a hydrogen atom changes its state from n = 3 to n = 2. Calculate the fractional change in the wavelength of light emitted, due to the recoil.
Consider an excited hydrogen atom in state n moving with a velocity υ(ν<<c). It emits a photon in the direction of its motion and changes its state to a lower state m. Apply momentum and energy conservation principles to calculate the frequency ν of the emitted radiation. Compare this with the frequency ν0 emitted if the atom were at rest.
In the Auger process an atom makes a transition to a lower state without emitting a photon. The excess energy is transferred to an outer electron which may be ejected by the atom. (This is called an Auger electron). Assuming the nucleus to be massive, calculate the kinetic energy of an n = 4 Auger electron emitted by Chromium by absorbing the energy from a n = 2 to n = 1 transition.
A hydrogen atom makes a transition from n = 5 to n = 1 orbit. The wavelength of photon emitted is λ. The wavelength of photon emitted when it makes a transition from n = 5 to n = 2 orbit is ______.
