Advertisements
Advertisements
प्रश्न
Find the radius and energy of a He+ ion in the states (a) n = 1, (b) n = 4 and (c) n = 10.
Advertisements
उत्तर
For He+ ion,
Atomic number, Z = 2
For hydrogen like ions, radius (r) of the nth state is given by
`r = (0.53 n^2)/ZÅ`
Here
Z= Atomic number of ions
n = Quantum number of the state
Energy (E) of the nth state is given by
`E_n = -(13.6 Z^2)/(n^2)`
(a)
for n = 1
Radius,
`r = (0.53xx(1)^2)/2`
`Å = 0.265 A^0`
Energy, En = `(-13.6 xx 4)/1`
= - 54.4 ev
(b)
For n = 4,
Radius, `r = (0.53xx16)/2 = 4.24 Å `
Energy, `E = (-13.6xx4)/16= -3.4 eV`
(c)
For n = 10,
`Radius, r = (0.53xx100)/2`
= 26.5 Å
Energy, E = `(-13.6 xx 4 )/100 = -0.544 eV`
APPEARS IN
संबंधित प्रश्न
Classically, an electron can be in any orbit around the nucleus of an atom. Then what determines the typical atomic size? Why is an atom not, say, a thousand times bigger than its typical size? The question had greatly puzzled Bohr before he arrived at his famous model of the atom that you have learnt in the text. To simulate what he might well have done before his discovery, let us play as follows with the basic constants of nature and see if we can get a quantity with the dimensions of length that is roughly equal to the known size of an atom (~ 10−10 m).
(a) Construct a quantity with the dimensions of length from the fundamental constants e, me, and c. Determine its numerical value.
(b) You will find that the length obtained in (a) is many orders of magnitude smaller than the atomic dimensions. Further, it involves c. But energies of atoms are mostly in non-relativistic domain where c is not expected to play any role. This is what may have suggested Bohr to discard c and look for ‘something else’ to get the right atomic size. Now, the Planck’s constant h had already made its appearance elsewhere. Bohr’s great insight lay in recognising that h, me, and e will yield the right atomic size. Construct a quantity with the dimension of length from h, me, and e and confirm that its numerical value has indeed the correct order of magnitude.
Which wavelengths will be emitted by a sample of atomic hydrogen gas (in ground state) if electrons of energy 12.2 eV collide with the atoms of the gas?
The minimum orbital angular momentum of the electron in a hydrogen atom is
Which of the following curves may represent the speed of the electron in a hydrogen atom as a function of trincipal quantum number n?
Which of the following products in a hydrogen atom are independent of the principal quantum number n? The symbols have their usual meanings.
(a) vn
(b) Er
(c) En
(d) vr
Find the binding energy of a hydrogen atom in the state n = 2.
A hydrogen atom emits ultraviolet radiation of wavelength 102.5 nm. What are the quantum numbers of the states involved in the transition?
A hydrogen atom in a state having a binding energy of 0.85 eV makes transition to a state with excitation energy 10.2 e.V (a) Identify the quantum numbers n of the upper and the lower energy states involved in the transition. (b) Find the wavelength of the emitted radiation.
Whenever a photon is emitted by hydrogen in Balmer series, it is followed by another photon in Lyman series. What wavelength does this latter photon correspond to?
A hydrogen atom in state n = 6 makes two successive transitions and reaches the ground state. In the first transition a photon of 1.13 eV is emitted. (a) Find the energy of the photon emitted in the second transition (b) What is the value of n in the intermediate state?
What is the energy of a hydrogen atom in the first excited state if the potential energy is taken to be zero in the ground state?
Suppose, in certain conditions only those transitions are allowed to hydrogen atoms in which the principal quantum number n changes by 2. (a) Find the smallest wavelength emitted by hydrogen. (b) List the wavelength emitted by hydrogen in the visible range (380 nm to 780 nm).
Find the temperature at which the average thermal kinetic energy is equal to the energy needed to take a hydrogen atom from its ground state to n = 3 state. Hydrogen can now emit red light of wavelength 653.1 nm. Because of Maxwellian distribution of speeds, a hydrogen sample emits red light at temperatures much lower than that obtained from this problem. Assume that hydrogen molecules dissociate into atoms.
Average lifetime of a hydrogen atom excited to n = 2 state is 10−8 s. Find the number of revolutions made by the electron on the average before it jumps to the ground state.
Show that the ratio of the magnetic dipole moment to the angular momentum (l = mvr) is a universal constant for hydrogen-like atoms and ions. Find its value.
A hydrogen atom in ground state absorbs a photon of ultraviolet radiation of wavelength 50 nm. Assuming that the entire photon energy is taken up by the electron with what kinetic energy will the electron be ejected?
Let En = `(-1)/(8ε_0^2) (me^4)/(n^2h^2)` be the energy of the nth level of H-atom. If all the H-atoms are in the ground state and radiation of frequency (E2 - E1)/h falls on it ______.
- it will not be absorbed at all.
- some of atoms will move to the first excited state.
- all atoms will be excited to the n = 2 state.
- no atoms will make a transition to the n = 3 state.
A hydrogen atom makes a transition from n = 5 to n = 1 orbit. The wavelength of photon emitted is λ. The wavelength of photon emitted when it makes a transition from n = 5 to n = 2 orbit is ______.
