Advertisements
Advertisements
प्रश्न
When a photon is emitted from an atom, the atom recoils. The kinetic energy of recoil and the energy of the photon come from the difference in energies between the states involved in the transition. Suppose, a hydrogen atom changes its state from n = 3 to n = 2. Calculate the fractional change in the wavelength of light emitted, due to the recoil.
Advertisements
उत्तर
Difference in energy in the transition from n = 3 to n = 2 is 1.89 eV ( = E).
If all this energy is used up in emitting a photon (i.e. recoil energy is zero).
Then,
`E = (hc)/lamda`
`rArr lamda = (hc)/E` ..........(i)
If difference of energy is used up in emitting a photon and recoil of atom, then let ER be the recoil energy of atom.
`E = (hc)/lamda + E_R`
`rArr lamda ' = (hc)/(E - E_R)` ............(ii)
Fractional change in the wavelength is given as,
`(Delta lamda)/lamda = (lamda'-lamda)/lamda`
`rArr (Deltalamda)/lamda = 1/lamda((hc)/(E-E_R ) - (hc)/E)`
`rArr (Delta lamda)/(lamda)=E/(hc) (hcE_R)/(E(E-E_R)) (therefore lamda = (hc)/E)`
`rArr (Deltalamda)/lamda = ((E_R)/(E- E_R))`
APPEARS IN
संबंधित प्रश्न
Classically, an electron can be in any orbit around the nucleus of an atom. Then what determines the typical atomic size? Why is an atom not, say, a thousand times bigger than its typical size? The question had greatly puzzled Bohr before he arrived at his famous model of the atom that you have learnt in the text. To simulate what he might well have done before his discovery, let us play as follows with the basic constants of nature and see if we can get a quantity with the dimensions of length that is roughly equal to the known size of an atom (~ 10−10 m).
(a) Construct a quantity with the dimensions of length from the fundamental constants e, me, and c. Determine its numerical value.
(b) You will find that the length obtained in (a) is many orders of magnitude smaller than the atomic dimensions. Further, it involves c. But energies of atoms are mostly in non-relativistic domain where c is not expected to play any role. This is what may have suggested Bohr to discard c and look for ‘something else’ to get the right atomic size. Now, the Planck’s constant h had already made its appearance elsewhere. Bohr’s great insight lay in recognising that h, me, and e will yield the right atomic size. Construct a quantity with the dimension of length from h, me, and e and confirm that its numerical value has indeed the correct order of magnitude.
If Bohr’s quantisation postulate (angular momentum = nh/2π) is a basic law of nature, it should be equally valid for the case of planetary motion also. Why then do we never speak of quantisation of orbits of planets around the sun?
Which wavelengths will be emitted by a sample of atomic hydrogen gas (in ground state) if electrons of energy 12.2 eV collide with the atoms of the gas?
When white radiation is passed through a sample of hydrogen gas at room temperature, absorption lines are observed in Lyman series only. Explain.
What will be the energy corresponding to the first excited state of a hydrogen atom if the potential energy of the atom is taken to be 10 eV when the electron is widely separated from the proton? Can we still write En = E1/n2, or rn = a0 n2?
In which of the following transitions will the wavelength be minimum?
In which of the following systems will the radius of the first orbit (n = 1) be minimum?
As one considers orbits with higher values of n in a hydrogen atom, the electric potential energy of the atom
Which of the following products in a hydrogen atom are independent of the principal quantum number n? The symbols have their usual meanings.
(a) vn
(b) Er
(c) En
(d) vr
Find the radius and energy of a He+ ion in the states (a) n = 1, (b) n = 4 and (c) n = 10.
(a) Find the first excitation potential of He+ ion. (b) Find the ionization potential of Li++ion.
Find the maximum Coulomb force that can act on the electron due to the nucleus in a hydrogen atom.
Suppose, in certain conditions only those transitions are allowed to hydrogen atoms in which the principal quantum number n changes by 2. (a) Find the smallest wavelength emitted by hydrogen. (b) List the wavelength emitted by hydrogen in the visible range (380 nm to 780 nm).
A hydrogen atom in ground state absorbs a photon of ultraviolet radiation of wavelength 50 nm. Assuming that the entire photon energy is taken up by the electron with what kinetic energy will the electron be ejected?
Consider an excited hydrogen atom in state n moving with a velocity υ(ν<<c). It emits a photon in the direction of its motion and changes its state to a lower state m. Apply momentum and energy conservation principles to calculate the frequency ν of the emitted radiation. Compare this with the frequency ν0 emitted if the atom were at rest.
Let En = `(-1)/(8ε_0^2) (me^4)/(n^2h^2)` be the energy of the nth level of H-atom. If all the H-atoms are in the ground state and radiation of frequency (E2 - E1)/h falls on it ______.
- it will not be absorbed at all.
- some of atoms will move to the first excited state.
- all atoms will be excited to the n = 2 state.
- no atoms will make a transition to the n = 3 state.
Positronium is just like a H-atom with the proton replaced by the positively charged anti-particle of the electron (called the positron which is as massive as the electron). What would be the ground state energy of positronium?
A hydrogen atom makes a transition from n = 5 to n = 1 orbit. The wavelength of photon emitted is λ. The wavelength of photon emitted when it makes a transition from n = 5 to n = 2 orbit is ______.
