Advertisements
Advertisements
प्रश्न
Predict the number of unpaired electrons in the square planar [Pt(CN)4]2− ion.
Advertisements
उत्तर
78Pt is located in group 10 of the periodic table and its configuration is 5d96s1. Hence the configuration of Pt2+ is d8.

The hybridisation for square planar structure is dsp2. Since the unpaired electrons in 5d pair up to form a vacant d-orbital for dsp2 hybridisation, there are no unpaired electrons.
APPEARS IN
संबंधित प्रश्न
On the basis of valence bond theory explain the nature of bonding in [CoF6]3 ion.
[NiCl4]2− is paramagnetic, while [Ni(CO)4] is diamagnetic, though both are tetrahedral. Why? (Atomic number of Ni = 28)
Explain on the basis of valence bond theory that [Ni(CN)4]2− ion with square planar structure is diamagnetic and the [NiCl4]2− ion with tetrahedral geometry is paramagnetic.
Discuss the nature of bonding in the following coordination entity on the basis of valence bond theory:
[CoF6]3−
Explain the geometry of `[Co(NH_3)_6]^(3+)` on the basis of hybridisation. (Z of Co = 27)
Using valence bond theory, explain the following in relation to the complexes given below:
\[\ce{[Mn(CN)6]^{3-}}\]
(i) Type of hybridisation.
(ii) Inner or outer orbital complex.
(iii) Magnetic behaviour.
(iv) Spin only magnetic moment value.
Using valence bond theory, explain the following in relation to the complexes given below:
\[\ce{[Co(NH3)6]^{3+}}\]
(i) Type of hybridisation.
(ii) Inner or outer orbital complex.
(iii) Magnetic behaviour.
(iv) Spin only magnetic moment value.
If orbital quantum number (l) has values 0, 1, 2 and 3, deduce the corresponding value of principal quantum number, n.
When the hybridization state of carbon changes from sp3 to sp2 and finally to sp, the angle between hybridized orbital will
As the s-character of hybridised orbital increases, the bond angle
Which of the following has square planar structures?
What is the no. of possible isomers for the octahedral complex [Co(NH3)2(C2O4)2]?
Valence bond theory is based on the assumption that the bonds formed between the metal ions and ligands are ______
The magnetic moment of [NiCl4]2− is ______.
[Atomic number: Ni = 28]
[Ni(CO)4] has tetrahedral geometry while [Ni(CN)4]2− has square planar, yet both exhibit diamagnetism. Explain.
[Atomic number: Ni = 28]
Which of the following are paramagnetic?
- [NiCl4]2−
- Ni(CO)4
- [Ni(CN)4]2−
- [Ni(H2O)6]2+
- Ni(PPh3)4
Choose the correct answer from the options given below:
