Advertisements
Advertisements
प्रश्न
Explain the following:
Silicon forms \[\ce{SiF^{2-}6}\] ion whereas corresponding fluoro compound of carbon is not known.
Advertisements
उत्तर
The bond dissociation energy decreases rapidly as the atomic size increases. Since the atomic size of carbon is much smaller (77 pm) as compared to that of silicon (118 pm), therefore, carbon-carbon bond dissociation energy is much higher (348 kJ mol–1) than that of silicon-silicon bond (297 kJ mol–1). Hence, because C – C bonds are much stronger as compared to Si-Si bonds, carbon has a much higher tendency for catenation than silicon.
APPEARS IN
संबंधित प्रश्न
Discuss the pattern of variation in the oxidation states of B to Tl.
Discuss the pattern of variation in the oxidation states of C to Pb.
Explain the following reaction.
Silicon is heated with methyl chloride at high temperature in the presence of copper.
Rationalise the given statement and give a chemical reaction:
Lead (IV) chloride is highly unstable towards heat.
Rationalise the given statement and give a chemical reaction:
Lead is known not to form an iodide, PbI4.
Classify the following oxide as neutral, acidic, basic or amphoteric:
CO
Classify the following oxide as neutral, acidic, basic or amphoteric:
Al2O3
Classify the following oxide as neutral, acidic, basic or amphoteric:
PbO2
Write suitable chemical equations to show the nature of the following oxide.
B2O3
Write suitable chemical equations to show the nature of the following oxide.
Al2O3
Catenation i.e., linking of similar atoms depends on size and electronic configuration of atoms. The tendency of catenation in Group 14 elements follows the order:
The linear shape of CO2 is due to:
(i) sp3 hybridisation of carbon.
(ii) sp hybridisation of carbon.
(iii) pπ – pπ bonding between carbon and oxygen.
(iv) sp2 hybridisation of carbon.
Explain the following:
CO2 is a gas whereas SiO2 is a solid.
Explain the following:
Silicon forms \[\ce{SiF^{2-}6}\] ion whereas corresponding fluoro compound of carbon is not known.
Explain the following:
BF3 does not hydrolyse.
The principal ore of lead is ______.
Which one of the following compounds of Group–14 elements is not known?
