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प्रश्न
Derive an expression to calculate molar mass of non-volatile solute by osmotic pressure measurement.
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उत्तर
For very dilute solution
Where π = `(n_2RT)/V`
π = Osmotic Pressure
n2 = Number of moles of solute
R = Gas constant
T = Absolute temperature
V = Volume of solution
n2 = `(W_2 ("Mass of solute"))/(M_2 ("Molar mass of solution"))`
M2 = `(W_2RT)/(πV)`
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संबंधित प्रश्न
Determine the osmotic pressure of a solution prepared by dissolving 2.5 × 10−2 g of K2SO4 in 2L of water at 25°C, assuming that it is completely dissociated.
(R = 0.0821 L atm K−1 mol−1, Molar mass of K2SO4 = 174 g mol−1)
A solution containing 15 g urea (molar mass = 60 g mol–1) per litre of solution in water has the same osmotic pressure (isotonic) as a solution of glucose (molar mass = 180 g mol–1) in water. Calculate the mass of glucose present in one litre of its solution.
Determine the osmotic pressure of a solution prepared by dissolving 25 mg of K2SO4 in 2 liter of water at 25°C, assuming that it is completely dissociated.
Define osmotic pressure.
Which of the following 0.1 M aqueous solutions will exert the highest osmotic pressure?
Define Semipermeable membrane
Calculate the mass of NaCl (molar mass = 58.5 g mol−1) to be dissolved in 37.2 g of water to lower the freezing point by 2°C, assuming that NaCl undergoes complete dissociation. (Kf for water = 1.86 K kg mol−1)
Calculate the mass of a compound (molar mass = 256 g mol−1) to be dissolved in 75 g of benzene to lower its freezing point by 0.48 K (Kf = 5.12 K kg mol−1).
Define the following term:
isotonic solution
Choose the most correct option.
A living cell contains a solution which is isotonic with 0.3 M sugar solution. What osmotic pressure develops when the cell is placed in 0.1 M KCl solution at body temperature?
Choose the most correct option.
The osmotic pressure of blood is 7.65 atm at 310 K. An aqueous solution of glucose isotonic with blood has the percentage (by volume)________.
Answer the following in one or two sentences.
A solution concentration is expressed in molarity and not in molality while considering osmotic pressure. Why?
Answer the following.
A solvent and its solution containing a nonvolatile solute are separated by a semipermeable membrane. Does the flow of solvent occur in both directions? Comment giving a reason.
Answer the following.
Explain reverse osmosis.
Which of the following statements is applicable for 0.1 M urea solution and 0.1 M sucrose solution?
Explain the osmotic pressure of a solution with the help of a thistle tube.
Explain the phenomenon of osmosis.
Define Osmosis.
Which of the following is a colligative property?
Two solutions have different osmotic pressures. The solution of higher osmotic pressure is called ____________.
20 g of a substance were dissolved in 500 mL of water and the osmotic pressure of the solution was found to be 600 mm of mercury at 15°C. The molecular weight of the substance is:
The average osmotic pressure of human blood is 7.8 bar at 37°C. What is the concentration of an aqueous NaCl solution that could be used in the blood stream?
Osmotic pressure of a solution is 0.0821 atm at a temperature of 300 K. The concentration in moles/litre will be:
A solution containing 10 g per dm3 of urea (molar mass 60 g mol−1) is isotonic with 5% solution of non-volatile solute, MB of solute is:
Which of the following statements is false?
In isotonic solutions:
(i) Solute and solvent both are same.
(ii) Osmotic pressure is same.
(iii) Solute and solvent may or may not be same.
(iv) Solute is always same solvent may be different.
Give an example of a material used for making semipermeable membrane for carrying out reverse osmosis.
Match the items given in Column I and Column II.
| Column I | Column II |
| (i) Saturated solution | (a) Solution having same osmotic pressure at a given temperature as that of given solution. |
| (ii) Binary solution | (b) A solution whose osmotic pressure is less than that of another. |
| (iii) Isotonic solution | (c) Solution with two components. |
| (iv) Hypotonic solution | (d) A solution which contains maximum amount of solute that can be dissolved in a given amount of solvent at a given temperature. |
| (v) Solid solution | (e) A solution whose osmotic pressure is more than that of another. |
| (vi) Hypertonic solution | (f) A solution in solid phase. |
Discuss biological and industrial importance of osmosis.
How can you remove the hard calcium carbonate layer of the egg without damaging its semiprermiable membrane? Can this egg be inserted into a bottle with a narrow neck without distorting its shape? Explain the process involved.
Which of the following colligative property can provide molar mass of proteins (or polymers or colloids) with greatest precision?
Which one of the following is a colligative property?
Osmotic pressure of a solution containing 2 g dissolved protein per 300 cm3 of solution is 20 mm of Hg at 27°C. The molecular mass of protein is ______.
Assertion (A) : Osmotic pressure is a colligative property.
Reason (R) : Osmotic pressure is proportional to the molality.
Determine the osmotic pressure of a solution prepared by dissolving 2.32 × 10−2 g of K2SO4 in 2L of solution at 25°C assuming that K2SO4 is completely dissociated.
(R = 0.082 L atm K−1 mol, Molar mass K2SO4 = 174 g mol−1)
Isotonic solutions are the solutions having the same ______.
A solution containing 10 g glucose has osmotic pressure 3.84 atm. If 10 g more glucose is added to the same solution, what will be its osmotic pressure? (Temperature remains constant)
Define reverse osmosis.
How will you determine molar mass of solute from osmotic pressure?
Write the condition of reverse osmosis.
